Emerging Carbon Nanotube-Based Nanomaterials for Stable and Dendrite-Free Alkali Metal Anodes:Challenges,Strategies,and Perspectives
作者机构:Provincial and Ministerial Co-construction of Collaborative Innovation Center for Non-Ferrous Metal New Materials and Advanced Processing TechnologyHenan Key Laboratory of Non-Ferrous Materials Science&Processing TechnologySchool of Materials Science and EngineeringHenan University of Science and TechnologyLuoyang 471023China Longmen LaboratoryLuoyang 471023China Key Laboratory of Function-Oriented Porous Materials of Henan ProvinceCollege of Chemistry and Chemical EngineeringLuoyang Normal UniversityLuoyang 471934China School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China School of Materials and EnergyUniversity of Electronic Science and Technology of ChinaChengdu 611731China
出 版 物:《Energy & Environmental Materials》 (能源与环境材料(英文))
年 卷 期:2023年第6卷第6期
页 面:50-72页
核心收录:
学科分类:0808[工学-电气工程] 08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)]
基 金:supported by the National Key Research and Development Program of China(2020YFB1713500) the Chinese 02 Special Fund(2017ZX02408003) Open Fund of State Key Laboratory of Advanced Refractories(SKLAR202210) the Foundation of Department of Science and Technology of Henan Province(212102210219)
主 题:alkali metal anodes carbon nanotube dendrite free electrochemical performance nanomaterials
摘 要:Alkali metals(Li,Na,and K)are promising candidates for high-performance rechargeable alkali metal battery anodes due to their high theoretical specific capacity and low electrochemical ***,the actual application of alkali metal anodes is impeded by the challenges of alkali metals,including their high chemical reactivity,uncontrolled dendrite growth,unstable solid electrolyte interphase,and infinite volume expansion during cycling *** carbon nanotube-based nanomaterials in alkali metal anodesis an effective solution to these *** nanomaterials have attracted widespread attention owing to their unique properties,such as their high specific surface area,superior electronic conductivity,and excellent mechanical *** the rapidly growing research enthusiasm for this topic in the last several years,we review recent progress on the application of carbon nanotube-based nanomaterials in stable and dendrite-free alkali metal *** merits and issues of alkali metal anodes,as well as their stabilizing strategies are ***,the relationships among methods of synthesis,nano-or microstructures,and electrochemical properties of carbon nanotube-based alkali metal anodes are systematically *** addition,advanced characterization technologies on the reaction mechanism of carbon nanotube-based nanomaterials in alkali metal anodes are also ***,the challenges and prospects for future study and applications of carbon nanotube-based AMAs in high-performance alkali metal batteries are discussed.