Copper-based bimetallic electrocatalysts for CO_(2) reduction:From mechanism understandings to product regulations
作者机构：Key Laboratory for Green Chemical Technology of Ministry of EducationHaihe Laboratory of Sustainable Chemical TransformationsSchool of Chemical Engineering and TechnologyTianjin UniversityTianjin300072China Joint School of National University of Singapore and Tianjin UniversityInternational Campus of Tianjin UniversityBinhai New CityFuzhou350207China
出 版 物：《Materials Reports(Energy)》 (材料导报（能源）（英文）)
年 卷 期：2023年第3卷第1期
页 面：19-34,I0002页
核心收录：
学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
基 金：financial support from National Na-ture Science Foundation of China(Nos.22078232 and 21938008) the Science and Technology Major Project of Tianjin(Nos.19ZXNCGX00030 and 20JCYBJC00870) Seed Foundation of Tianjin University(2022XJS-0051)
主 题：Copper Bimetallic electrocatalysts Carbon dioxide reduction Mechanism Product regulations
摘 要：Electrocatalytic carbon dioxide reduction reaction(CO_(2) RR)is a promising method to solve current environment and energy ***-based catalysts have been widely studied for converting CO_(2) into value-added hy-drocarbon *** monometallic catalyst has been proved to have some shortcomings,including relatively high energy barriers and diverse reaction pathways,leading to low reaction activities and poor product selec-tivity,*** copper-based bimetallic tandem catalysts have attracted extensive attentions due to their special catalyst structure,which can be easily regulated to achieve high CO_(2) RR reactivity and product *** the development of quantum chemistry calculations and spectroscopic characterization methods,deep understandings of CO_(2) RR from the mechanism perspective provide a broad horizon for the design of effi-cient *** review offers a good summary of reaction mechanisms and product regulation strategies over copper-based bimetallic catalysts,along with a brief discussion on future directions towards their practical applications.
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