CO_(2)utilization in syngas conversion to dimethyl ether and aromatics:Roles and challenges of zeolites-based catalysts

作     者：Ali A.Al-Qadri Galal A.Nasser Haruna Adamu Oki Muraza Tawfik A.Saleh Ali A.Al-Qadri;Galal A.Nasser;Haruna Adamu;Oki Muraza;Tawfik A.Saleh

作者机构：Department of Chemical EngineeringKing Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia Interdisciplinary Research Center for Hydrogen and Energy Storage(IRC-HES)King Fahd University of Petroleum&MineralsDhahran 31261Saudi Arabia Department of Environmental Management Technologyand Department of ChemistryAbubakar Tafawa Balewa UniversityBauchiNigeria Department of ChemistryKing Fahd University of Petroleum and MineralsDhahran 31261Saudi Arabia 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2023年第79卷第4期

页      面：418-449页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：the support provided by the Interdisciplinary Research Center for Hydrogen and Energy Storage(IRC-HES) 

主　　题：Clean fuel DME Aromatics Bifunctional catalyst CO_(2)mitigation 

摘      要：Several studies have proven a strong correlation between global warming and CO_(2)***,38 billion tons of CO_(2)are approximately emitted into the *** CO_(2)via chemical conversion to clean fuels and value-added aromatics can substantially contribute to controlling the *** the thermodynamic and environmental limitations of hydrogenation of CO_(2)alone to value-added aromatics and fuels,CO_(2)utilization has currently emerged as a promising and practical approach for the production of fuels and aromatics with simultaneous utilization of both CO and CO_(2)*** such,the approach is economically ***_(2)could be converted directly to fuels by the hydrogenation process or as a part of a syngas *** ether(DME)is a clean fuel with a higher energy density,which could be used as a substituent for several fuels such as *** the same vein,value-added aromatics such as benzene,toluene,and xylene(BTX)can be produced from a similar ***,we report a review that collects the most recent studies for the conversion of CO_(2)to DME and aromatics via zeolite-based bifunctional *** highlighted the main routes for producing DME and aromatics,as well as thoroughly discussed the conducted studies on CO_(2)hydrogenation and CO_(2)-rich syngas utilized as feedstock for conversion to DME and *** CO_(2)hydrogenation mostly occurs through the methanol-mediated reaction route but is most often limited by low selectivity and catalyst deactivation,particularly in the utilization of CO_(2)alone for the reduction *** review takes an overview of the progress made so far and concluded by identifying the roles and challenges of zeolite-based catalysts for CO_(2)utilization and conversion to DME and ***,despite the incredible growth the field received in the last couple of years,however,many research challenges and opportunities associated with this process are still abou