Coordination-driven self-assembly of dibenzo-18-crown-6 functionalized Pt(Ⅱ) metallacycles

作     者：Zibin Zhang Yu Yao Lang He Tao Hong Shijun Li Feihe Huang Peter J.Stang Zibin Zhang;Yu Yao;Lang He;Tao Hong;Shijun Li;Feihe Huang;Peter J.Stang

作者机构：College of MaterialChemistry and Chemical EngineeringHangzhou Normal UniversityHangzhou 311121China State Key Laboratory of Chemical EngineeringStoddart Institute of Molecular ScienceDepartment of ChemistryZhejiang UniversityHangzhou 310027China Green Catalysis Center and College of ChemistryZhengzhou UniversityZhengzhou 450001China Department of ChemistryUniversity of UtahSalt Lake CityUT 84112United States 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2023年第34卷第2期

页      面：158-160页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China (Nos. 22071040 and 21773052) the Natural Science Foundation of Zhejiang Province (No. LY22B040001) the Science & Technology Innovation Program of Zhejiang Province (No. 2018R52051) the National Natural Science Foundation of China (Nos. 22035006 and 21620102006) for financial support 

主　　题：Crown ethers Metallacycles Cation receptors Self-assembly 

摘      要：Coordination-driven self-assembly was used to construct two metallacycles of a dicarboxylatefunctionalized dibenzo-18-crown-6 in combination with either a 0° anthracene-based clip-type acceptor or a 60° phenanthrene-based acceptor. The angularities of these moieties make them suitable for the formation of a [2 + 2] rectangle and a [3 + 3] triangle, respectively. The synthesis, characterization and host-guest chemistry of two metallacycles were described and supported by31P{1H},1H NMR spectra and electrospray mass spectrometry.