Exploring the contribution of oxygen reduction reaction to Mg corrosion by modeling assisted local analysis

作     者：Cheng Wang Wen Xu Daniel Höche Mikhail L.Zheludkevich Sviatlana V.Lamaka 

作者机构：Institute of Surface ScienceHelmholtz-Zentrum HereonGeesthacht 21502Germany Institute for Materials ScienceFaculty of EngineeringKiel UniversityKiel 24103Germany 

出 版 物：《Journal of Magnesium and Alloys》 (镁合金学报（英文）)

年 卷 期：2023年第11卷第1期

页      面：100-109页

核心收录：

学科分类：08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：the China Scholarship Council for the award of fellowship and funding(No.201806310128 201908510177) 

主　　题：Local oxygen concentration Oxygen reduction reaction Mg corrosion NaCl electrolyte Hydrogen evolution reaction Numerical model 

摘      要：Oxygen reduction reaction(ORR)has been disclosed in recent studies as a significant secondary cathodic process during magnesium *** work elaborates on the contribution of ORR to the total corrosion process of pure Mg at different impurity levels in NaCl electrolyte with the assistance of local techniques.A finite element based numerical model taking into account the contribution of ORR during the corrosion of the Mg test materials has been designed in this study considering the local oxygen *** computational simulations were calibrated based on the experimental data and evaluated ***,the simultaneous monitoring of local concentration of H_(2) and O_(2),and the combined modeling study reveal the relation between ORR and hydrogen evolution reaction.