Impact of severe plastic deformation on kinetics and thermodynamics of hydrogen storage in magnesium and its alloys
作者机构：WPIInternational Institute for Carbon-Neutral Energy Research(WPI-I2CNER)Kyushu UniversityFukuokaJapan International Research Center for Hydrogen EnergyKyushu UniversityFukuokaJapan Departamento de Engenharia de MateriaisUniversidade Federal de São CarlosSao Carlos-SPBrazil Department of Materials Science and EngineeringMonash UniversityClaytonVIC 3800Australia Department of Mechanical Engineeringthe University of Western AustraliaCrawleyWA 6009Australia School of Applied SciencesUniversity of Campinas(UNICAMP)LimeiraSão PauloBrazil Institut NéelCNRS&UGA38042 GrenobleFrance JOMI-LEMAN SA74890 FessyFrance Universitéde LorraineLaboratory of Excellence on Design of Alloy Metals for low-mass Structures(DAMAS)MetzF-57070France Universitéde LorraineLaboratoire d’Etude des Microstructures et de Mécanique des Matériaux(LEM3 UMR 7239)MetzF-57070France Graduate School of EngineeringKyushu Institute of TechnologyKitakyushuJapan Magnesium Research CenterKumamoto UniversityKumamotoJapan Synchrotron Light Application CenterSaga UniversitySagaJapan Hydrogen Research InstituteUniversitédu QuébecàTrois-Rivières3351 des ForgesTrois-RivièresQC G9A 5H7Canada Hefei General Machinery Research InstituteHefei 230031China Institute of Advanced Wear&Corrosion Resistance and Functional MaterialsJinan UniversityGuangzhou 510632China Department of Materials PhysicsEötvös UniversityBudapestH-1518P.O.B.32BudapestHungary Faculty of PhysicsUniversity of ViennaBoltzmanngasse 5A-1090 WienAustria
出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)
年 卷 期：2023年第146卷第15期
页 面：221-239页
核心收录：
学科分类：08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）]
基 金：supported in part by the Light Metals Educational Foundation of Japan,and in part by the MEXT,Japan through Grants-in-Aid for Scientific Research on Innovative Areas(Nos.JP19H05176&JP21H00150) the Challenging Research Exploratory(Grant No.JP22K18737) W.J.Botta is grateful to the Brazilian agencies FAPESP(Grant No.2013/05987-8) CNPq(Grant Nos.421181-2018-4 and 307397-2019-0) the financial support and to the Laboratory of Structural Characterization(LCE-DEMa-UFSCar)for general electron microscopy facilities.R.Floriano thanks for the financial support from FAPESP(Grant No.2022/01351-0) support from the French State through the ANR-21-CE08-0034-01 project as well as the program“Investment in the future”operated by the National Research Agency(ANR) referenced under No.ANR-11-LABX-0008-01(Labex DAMAS) support from the National Natural Science Foundation of China(Grant No.52171205) support from the National Natural Science Foundation of China(Grant No.52071157)
主 题：Severe plastic deformation(SPD) Nanostructured materials Ultrafine-grained(UFG)materials Magnesium hydride(MgH_(2)) Magnesium-based alloys Hydrogen absorption Hydrogenation kinetics Hydrogen storage thermodynamics
摘 要：Magnesium and its alloys are the most investigated materials for solid-state hydrogen storage in the form of metal hydrides,but there are still unresolved problems with the kinetics and thermodynamics of hydrogenation and dehydrogenation of this group of *** plastic deformation(SPD)methods,such as equal-channel angular pressing(ECAP),high-pressure torsion(HPT),intensive rolling,and fast forging,have been widely used to enhance the activation,air resistance,and hydrogenation/dehydrogenation kinetics of Mg-based hydrogen storage materials by introducing ultrafine/nanoscale grains and crystal lattice *** severely deformed materials,particularly in the presence of alloying additives or second-phase nanoparticles,can show not only fast hydrogen absorption/desorption kinetics but also good cycling *** was shown that some materials that are apparently inert to hydrogen can absorb hydrogen after SPD ***,the SPD methods were effectively used for hydrogen binding-energy engineering and synthesizing new magnesium alloys with low thermodynamic stability for reversible low/room-temperature hydrogen storage,such as nanoglasses,high-entropy alloys,and metastable phases including the high-pressureγ-MgH2 *** work reviews recent advances in the development of Mg-based hydrogen storage materials by SPD processing and discusses their potential in future applications.
维普期刊数据库