STRUCTURAL TRANSFORMATION INDUCED BY MECHANICALLY DRIVEN ALLOYING AND SUBSEQUENT MAGNETIC PROPERLIESOF THE Fe-Cu SYSTEM

作     者：Y.Z.Yang Y.HLuo Q.S.Li Y.L.Zhu X.M.Ma Y.D.Dong Y.Z.Chuang 

作者机构：Guangdong Univ of Technology Guangzhou China 

出 版 物：《Acta Metallurgica Sinica(English Letters)》 (金属学报（英文版）)

年 卷 期：1998年第11卷第2期

页      面：128-136页

核心收录：

学科分类：08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

主　　题：mechanical alloying Mossbauer effect Fe-Cu alloy magnetic measurement 

摘      要：The structural transformation in Fe-Cu powder induced by mechanically driven alloying has been monitored by the lattice constant measurements and Mossbauer spectroscopy. For the samples with Cu higher than 75at.% Mossbauer the spectra show a broad paramagnetic doublet; for samples with 50 and 60at.%Cu a new broad ferromagnetic sextet; for those with less than 30at.%Cu similar to those of α-Fe. The main peaks of the hyperfine field distribution significantly broaden and shift to a lower position with increasing Cu content due to the complex environments of iron atoms in the solid solutions and the reduction in the nearest neighbor Fe of a cental Fe atom, respectively. The saturation magnetization of Fe-Cu alloys monotonously decreases with Cu content. The complex composition dependence of coercive field for the milled samples is discussed with respect to the solid dissolution, grain size, interfacial state etc.. The increase of lattice constants with the solute content in the two terminal solid solutions has been explained by the volume-size factor theory or magnetovolume effect.