Geochemistry of rare earth elements in cobalt-rich crusts from the Mid-Pacific M seamount
Geochemistry of rare earth elements in cobalt-rich crusts from the Mid-Pacific M seamount作者机构:Institute of Oceanology Chinese Academy of Sciences Key Lab of Marine Sedimentology and Environmental Geology of State Oceanic Administration First Institute of Oceanography Graduate University of Chinese Academy of Sciences
出 版 物:《Journal of Rare Earths》 (稀土学报(英文版))
年 卷 期:2009年第27卷第1期
页 面:169-176页
核心收录:
学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)]
基 金:supported by the National Natural Science Foundation of China(40704029 40376016) China International Science and Technology Cooperation Project (2006DFB21620) the Young People Marine Science Foundation of State Oceanic Administration (2005304)
主 题:rare earth elements cobalt-rich crusts Mid-Pacific ocean M seamount
摘 要:Rare earth elements(REEs) and major elements of 25 cobalt-rich crusts obtained from different depths of Mid-Pacific M seamount were analyzed using inductively coupled plasma-atomic emission spectrometer and gravimetric *** results showed that they were hydrogenous crusts with average ∑REE content of 2084.69 μg/g and the light REE(LREE)/heavy REE(HREE) ratio of *** shale-normalized REE patterns showed positive Ce *** total content of strictly trivalent REEs increased with water *** Ce content and LREE/HREE ratios in Fe-Mn crusts above 2000 m were lower than those below 2000 *** change in REE with water depth could be explained by two processes:adsorptive scavenging by setting matters and behaviors of REE in ***, the Ce abundance took no obvious correlation with water depth reflects the constant Ce *** Ce in crusts existed mainly as Ce(IV), implying that the oxidative-enriching process was controlled by kinetic factors.