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Structural characteristics,dispersion,and modification of fibrous brucite

Structural characteristics,dispersion,and modification of fibrous brucite

作     者:Xi Cao Xiu-yun Chuan 

作者机构:Key Laboratory of Orogen and Crust Evolution of the Education Ministry of ChinaSchool of Earth and Space SciencesPeking University 

出 版 物:《International Journal of Minerals,Metallurgy and Materials》 (矿物冶金与材料学报(英文版))

年 卷 期:2014年第21卷第1期

页      面:82-88页

核心收录:

学科分类:08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 

基  金:financially supported by the National Natural Science Foundation of China(Nos.51274015 and 40972027) 

主  题:fibrous brucite dispersion nanofibers surface treatment modification 

摘      要:Fibrous bmcite has very unique structure and physical properties. Brucite fibers were exfoliated into single nanofibers by using dioctyl sodium sulfosuccinate (AOT) as a dispersant through mechanical agitation and ultrasonic dispersion; and then, the nanofibers were modified by stearic acid and (3-aminopropyl)triethoxysilane (y-APS) compound modification agent. The nanofibers were characterized by using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and thermal gravimetric analysis. It is found that AOT has good effect on the dispersion. The single fiber has a consis- tent morphology, and fibrous bmcite is dispersed and modified without destroying the crystal structure. Infrared and thermal analysis shows that the surface modification of fibrous brucite is achieved by forming chemical bonds between the coupling agent and magnesium hydroxide.

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