Porous Metal-Organic Framework-Polymer Composites Using High Internal Phase Emulsion Templates: A Review

作     者：Yue Qiu Jin-Jin Li Ling Zhao Zhenhao Xi Weikang Yuan Yue Qiu;Jin-Jin Li;Ling Zhao;Zhenhao Xi;Weikang Yuan

作者机构：State Key Laboratory of Chemical EngineeringSchool of Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China Shanghai Key Laboratory of Multiphase Materials Chemical EngineeringEast China University of Science and TechnologyShanghai 200237China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2022年第41卷第12期

页      面：60-69页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：supported by the National Natural Science Foundation of China (21808140, 21978089) Shanghai Rising-Star Program (22QA1402800) the Fundamental Research Funds for the Central Universities 

主　　题：high internal phase emulsion(HIPE) metal-organic frameworks(MOFs) adsorption and separation heterogeneous catalysis bioengineering 

摘      要：As promising engineering materials for green and sustainable processes, porous metalorganic framework(MOF)-polymer composites show great potential in applications, including adsorption, separation, catalysis, and bioengineering. Owing to the mild and scalable operation, porous polymeric materials derived from high internal phase emulsion templates(polyHIPE) have received great interests in recent decades. In this contribution, research progress of the preparation of porous MOF@polyHIPE composites and their applications are reviewed, highlighting how can MOF particles be shaped by HIPE templates, in particular the polymerizable ones. Four different emulsion templates stabilized by MOFs and the applications of corresponding MOF@polyHIPE are included. Hopefully,both the state-of-art and future directions present herein can give rise to the development of highperformance porous MOF@polyHIPEs.