Investigation on catalytic distillation for ethyl acetate production with different catalytic packing structures

作     者：Zhiwei Wang Yu Zhang Zhi Zhang Daowei Zhou Zhikai Cao Yong Sha Zhiwei Wang;Yu Zhang;Zhi Zhang;Daowei Zhou;Zhikai Cao;Yong Sha

作者机构：Department of Chemical and Biochemical EngineeringCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005China 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2023年第53卷第1期

页      面：63-72页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 0702[理学-物理学] 

基　　金：support provided by National Natural Science Foundation of China(21978243). 

主　　题：Catalytic packing Ethyl acetate Catalytic distillation Mass transfer Esterification Reaction kinetics 

摘      要：The catalytic packing is the core component of the catalytic distillation,and how the catalyst exists in the packing has significant influence on the process.To investigate the effect of catalyst packings on the catalytic distillation process,the classical ethyl acetate reactive distillation system was utilized,and a supported catalytic packing(SCP)was prepared in comparison with the conventional tea-bag catalytic packing(TBP).Laboratory scale experiments showed that the ethyl acetate conversion of the SCP was superior to the TBP at a low catalyst loading.The effects of reaction kinetics,mass transfer performance and actual catalytic efficiency of the packings on this process were regarded as reasons and studied by combining the experiments and numerical simulation.Results suggested that the relatively immediate“in-situ separationcaused by the rapid reaction kinetics and better mass transfer performance of SCP may be a main reason for the difference of the conversion.