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A cobalt(Ⅱ)porphyrin with a tethered imidazole for efficient oxygen reduction and evolution electrocatalysis

A cobalt(Ⅱ) porphyrin with a tethered imidazole for efficient oxygen reduction and evolution electrocatalysis

作     者:Xialiang Li Ping Li Jindou Yang Lisi Xie Ni Wang Haitao Lei Chaochao Zhang Wei Zhang Yong-Min Lee Weiqiang Zhang Shunichi Fukuzumi Wonwoo Nam Rui Cao Xialiang Li;Ping Li;Jindou Yang;Lisi Xie;Ni Wang;Haitao Lei;Chaochao Zhang;Wei Zhang;Yong-Min Lee;Weiqiang Zhang;Shunichi Fukuzumi;Wonwoo Nam;Rui Cao

作者机构:Key Laboratory of Applied Surface and Colloid ChemistryMinistry of EducationSchool of Chemistry and Chemical EngineeringShaanxi Normal UniversityXi'an 710119 ShaanxiChina Department of Chemistry and Nano ScienceEwha Womans UniversitySeoul 03760Republic of Korea 

出 版 物:《Journal of Energy Chemistry》 (能源化学(英文版))

年 卷 期:2023年第76卷第1期

页      面:617-621,I0015页

核心收录:

学科分类:081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 

基  金:the support from the National Natural Science Foundation of China(21773146,22171176 and 22102092) the Fok Ying-Tong Education Foundation for Outstanding Young Teachers in University the Research Funds of Shaanxi Normal University the Fundamental Research Funds for the Central Universities the NRF of Korea(NRF-2021R1A3B1076539 and NRF-2020R1I1A1A01074630) 

主  题:Molecular electrocatalysis Cobalt porphyrin Axial ligand effect Oxygen reduction reaction Oxygen evolution reaction 

摘      要:Electrocatalytic oxygen reduction and evolution reactions are involved in new energy conversion and storage technologies,such as various fuel cells and metal-air batteries and also water splitting devices[1,2].However,both reactions are very slow in kinetics,and thus catalysts are required[3,4].

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