Relationship between elements migration ofα-AlFeMnSi phase and micro-galvanic corrosion sensitivity of Al-Zn-Mg alloy
α-AlFeMnSi相中元素扩散对Al–Zn–Mg合金微电偶腐蚀敏感性的影响作者机构:Beijing Advanced Innovation Center for Materials Genome EngineeringInstitute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China China Electric Power Research InstituteBeijing 100192China
出 版 物:《International Journal of Minerals,Metallurgy and Materials》 (矿物冶金与材料学报(英文版))
年 卷 期:2023年第30卷第1期
页 面:112-121页
核心收录:
学科分类:0806[工学-冶金工程] 08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)]
基 金:supported by the National Natural Science Foundation of China(No.52125102) the Fundamental Research Funds for the Central Universities(No.FRF-TP-20-01B) the Guangdong Basic and Applied Basic Research Foundation(No.2020B1515120093) the Special Fund Support for Taishan Industrial Leading Talents Project
主 题:Al-Zn-Mg alloy corrosion behavior α-AlFeMnSi phase first principles calculations
摘 要:First principles calculations and scanning Kelvin probe force microscopy(SKPFM)were used to investigate the effect of elements migration ofα-AlFeMnSi phase on micro-galvanic corrosion behavior of Al-Zn-Mg *** simulation results showed that the average work function difference between theα-AlFeMnSi phase and Al matrix decreased from 0.232 to 0.065 eV due to the synchronous migration of elements ***,as the elements Fe-Si migration during the extrusion process,the average Volta potential difference detected by SKPFM between theα-AlFeMnSi phase and Al matrix dropped down to 432.383 mV from 648.370 ***,the elements migration reduced the micro-galvanic corrosion sensitivity of Al-Zn-Mg *** reach the calculated low micro-galvanic tendency betweenα-AlFeMnSi phase and Al matrix,the diffusion of Mn should be promoted during extruding process.