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All-solid-state thin-film batteries based on lithium phosphorus oxynitrides

作     者:Wangqi Dai Yan Qiao Ziqiang Ma Tian Wang Zhengwen Fu Wangqi Dai;Yan Qiao;Ziqiang Ma;Tian Wang;Zhengwen Fu

作者机构:Shanghai Key Laboratory of Molecular Catalysis and Innovative MaterialsDepartment of ChemistryFudan UniversityShanghai 200433People’s Republic of China Nano Science and Technology InstituteUniversity of Science and Technology of ChinaSuzhou 215123People’s Republic of China 

出 版 物:《Materials Futures》 (材料展望(英文))

年 卷 期:2022年第1卷第3期

页      面:34-52页

核心收录:

学科分类:0808[工学-电气工程] 08[工学] 

基  金:financially supported by the NSAF(Grant No.U20A20336) Tianmu Lake Institute of Advanced Energy Storage Technologies Scientist Studio Program[No.TIES-SS0002] 

主  题:LiPON solid electrolyte solid thin-film battery interfacial property preparation method 

摘      要:Lithium phosphorus oxygen nitrogen(LiPON)as solid electrolyte discovered by Bates et al in the 1990s is an important part of all-solid-state thin-film battery(ASSTFB)due to its wide electrochemical stability window and negligible low electronic ***,the ionic conductivity of LiPON about 2×10^(−6) S cm^(−1) at room temperature is much lower than that of other types of solid electrolytes,which seriously limits the application of *** review summarizes the research and progress in ASSTFBs based on LiPON,in the solid-state electrolyte of LiPON-derivatives with adjustable chemical compositions of the amorphous structure for the improvement of the ionic conductivity and electrochemical stability,in the critical interface issues between LiPON and electrodes,and in preparation methods for *** review is helpful for people to understand the interface characteristics and various preparation methods of LiPON in *** key issues to be addressed concern how to develop solid-state electrolyte films with high conductivity and high-quality interface engineering as well as large-scale preparation technology,so as to realize the practical application of highly integrated ASSTFBs.

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