Chemiluminescence behavior of sodium hydrogen carbonate in the potassium permanganate-hydrogen peroxide reaction

作     者：CHEN Hui1,2,LU Chao1,LI RuiBo1,GUO GuangSheng1 & LIN Jin-Ming2 1State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology,Beijing 100029,China 2Department of Chemistry,Tsinghua University,Beijing 100084,China 

作者机构：State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Beijing China Department of Chemistry Tsinghua University Beijing China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2010年第53卷第8期

页      面：1784-1792页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：support from the National Natural Science Foundation of China (209350002) the National Basic Research Program of China (2007CB714507) 

主　　题：chemiluminescence potassium permanganate emitting species energy transfer 

摘      要：Chemiluminescence (CL) phenomenon of hydrogen peroxide with potassium permanganate in the presence of sodium hydrogen carbonate was *** of the surfactant on the CL system were *** surfactants could effectively increase the CL *** scavengers and organic reagents such as nitro blue tetrazolium chloride (NBT),cytochrome c,sodium azide,ascorbic acid,thiourea,tert-butanol and dimethyl sulphoxide were used to study the emitting *** emission spectrum was recorded and the results showed that the maximal emission wavelengths of NaHCO3-H2O2-KMnO4 system were 440 and 634 *** mechanism was discussed based on electron spin resonance (ESR) spectra,fluorescence spectra and UV-vis absorption *** addition of rhodamine B or uranine into this CL system enhanced the CL *** was due to part of the energy transfer from singlet oxygen and excited triplet dimers of two CO2 molecules to rhodamine B or *** CL could be induced by excited rhodamine B or uranine.