Chlorinated Effects of Double-Cable Conjugated Polymers on the Photovoltaic Performance in Single-Component Organic Solar Cells
Chlorinated Effects of Double-Cable Conjugated Polymers on the Photovoltaic Performance in Single-Component Organic Solar Cells作者机构:Hubei Engineering Technology Research Center of Optoelectronic and New Energy MaterialsHubei Key Laboratory of Plasma Chemistry and Advanced MaterialsSchool of Materials Science and EngineeringWuhan Institute of TechnologyWuhan430205China Beijing Advanced Innovation Center for Soft Matter Science and Engineering&State Key Laboratory of Organic-Inorganic CompositeBeijing University of Chemical TechnologyBeijing100029China
出 版 物:《高分子科学:英文版》 (Chinese Journal of Polymer Science)
年 卷 期:2023年第41卷第2期
页 面:187-193页
核心收录:
学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学]
基 金:the National Natural Science Foundation of China(Nos.51973169,51703172 and 52073016) the Open Project Program of Wuhan National Laboratory for Optoelectronics(No.2020WNLOKF015) the science foundation of Wuhan Institute of Technology(No.K202025)
主 题:Double-cable conjugated polymer Chlorination Single-component organic solar cells
摘 要:The recently emerged double-cable conjugated polymers have come into focus due to their significantly improved power conversion efficiencies (PCEs) in single-component organic solar cells (SCOSCs). In this work, the effect of chlorination in double-cable conjugated polymers with linear benzodithiophene backbone and pendant perylene bisimide on the photovoltaic performance in SCOSCs has been studied. After introducing chlorine atoms into conjugated side chains, the highest occupied molecular orbital level of the conjugated polymers is down-shifted, thus resulting in a higher open-circuit voltage. As a result, the chlorinated double-cable conjugated polymer exhibits improved photovoltaic performance from 3.46% to 3.57%.