New routes for the construction of strong metal-support interactions

作     者：Hai Wang Liang Wang Feng-Shou Xiao 

作者机构：Key Lab of Biomass Chemical Engineering of Ministry of EducationCollege of Chemical and Biological EngineeringZhejiang UniversityHangzhou310027China College of ChemistryZhengzhou UniversityZhengzhou 450001China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2022年第65卷第11期

页      面：2051-2057页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：supported by the National Natural Science Foundation of China(U21B20101 and 21932006) China National Postdoctoral Program for Innovative Talent(BX2021256) China Postdoctoral Science Foundation(2021M700119) 

主　　题：strong metal-support interaction supported catalyst metal nanoparticles heterogeneous catalysis 

摘      要：Supported metal nanoparticles(NPs)on solid carriers are highly efficient catalysts in many industrial ***,the sintering and/or leaching of metal NPs occurred under harsh reaction conditions that caused the catalyst *** metal-support interactions(SMSIs)serve as an effective method to stabilize the metal NPs against sintering and leaching,which have been extensively *** addition to the classical route to construct SMSIs via high-temperature reduction treatments,new routes have emerged recently to extend the scope of catalysts with SMSIs and optimized their catalytic *** this review,we briefly summarize these routes that avoid the high-temperature reduction treatments for the construction of *** significant advantages in stabilizing metal NPs,modulating the geometric/electronic structure of metal species,and the mechanism on the SMSI formation are particularly ***,the current challenges and developing trends in the construction of SMSIs for achieving more efficient catalysts are outlooked.