Porous carbon nanofibers derived from low-softening-point coal pitch towards all-carbon potassium ion hybrid capacitors
Porous carbon nanofibers derived from low-softening-point coal pitch towards all-carbon potassium ion hybrid capacitors作者机构:School of Materials Science and EngineeringUniversity of JinanJinan250022China
出 版 物:《Rare Metals》 (稀有金属(英文版))
年 卷 期:2022年第41卷第11期
页 面:3706-3716页
核心收录:
学科分类:080801[工学-电机与电器] 0808[工学-电气工程] 0809[工学-电子科学与技术(可授工学、理学学位)] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0703[理学-化学]
基 金:financially supported by the National Natural Science Foundation of China(Nos.52072151 and 52171211) Taishan Scholars(No.ts201712050) Jinan Independent Innovative Team(No.2020GXRC015) the Natural Science Doctoral Foundation of Shandong Province(No.ZR2019BB057) the Major Program of Shandong Province Natural Science Foundation(No.ZR2021ZD05)
主 题:Potassium ion hybrid capacitors(PIHC) Low-softening-point coal pitch Carbon nanofibers(CNF) Dual-carbon devices Long durability
摘 要:Potassium ion hybrid capacitors(PIHC)have promising applications in medium and large-scale energy storage systems due to their high energy/power density,abundant potassium resource and low ***,the slow kinetics of battery-type anodes originating from the large-size K+results in a mismatch between the two electrodes,rendering the modest energy density of ***,we first develop an electrospinning strategy to successfully synthesize fibrous precursor by using the HNO_(3)pre-oxidized low-softening-point coal pitch as the low-cost raw *** further carbonization or KOH activation,the two types of carbon nanofibers(CNF)are fabricated as anode and cathode materials,respectively,towards the dual-carbon PIHC *** to its threedimensional interconnected porous conducting network and large layer spacing,the resulted CNF anode material is endowed with high reversible capacities,excellent rate and long cycle ***,the activated CNF cathode with a large surface area of 2169 m^(2)·g^(-1)exhibits excellent capacitive performance.A PIHC constructed with the two fibrous electrodes delivers an energy density of110.0 Wh·kg^(-1)at 200.0 W kg^(-1),along with a capacitance retention of 83.5%after 10,000 cycles at 1.0 A·g^(-1).The contribution here provides a cost-efficiency avenue and platform for advanced dual-carbon PIHC.