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Controllable Strong and Ultralight Aramid Nanofiber‑Based Aerogel Fibers for Thermal Insulation Applications

作     者:Mengmeng Li Xian Chen Xiuting Li Jie Dong Xin Zhao Qinghua Zhang 

作者机构:State Key Laboratory for Modification of Chemical Fibers and Polymer MaterialsCollege of Materials Science and EngineeringDonghua UniversityShanghai 201620People’s Republic of China 

出 版 物:《Advanced Fiber Materials》 (先进纤维材料(英文))

年 卷 期:2022年第4卷第5期

页      面:1267-1277页

核心收录:

学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)] 

基  金:supported by the National Natural Science Foundation of China(NSFC)(21975040) the Scientific Research Innovation Plan of Shanghai Education Commission(2019-01-07-00-03-E00001) the Fundamental Research Funds for the Central Universities and the Graduate Student Innovation Fund of Donghua University(CUSF-DH-D-2021007) 

主  题:ANFs High mechanical properties Aerogel fiber Thermal insulation 

摘      要:High-performance polymer-based aerogel fibers with ultrahigh porosity,mechanical robustness and outstanding thermal stability are demanded for applying in effective thermal insulation devices,especially in harsh ***,the poor mechanical properties and thermal stability of the commonly reported polymer-based aerogel fibers restricted their applications in many *** a special nano-build-block,aramid nanofiber-based aerogel fiber is expected to conquer this problem in virtue of the outstanding performance,intrinsically related to aramid ***,a series of aramid nanofiber-based aerogel fibers were fabricated via a facial wet-spinning method combined with freeze-drying *** effects of coagulation bath temperature and the solid contents of the spinning precursors on their morphologies and mechanical properties were systematically *** obtained aerogel fibers possessed high porosity(92%),good mechanical prop-erties(tensile strength~8.1 MPa)and high specific surface area(~239 m^(2)/g).Meanwhile,the woven textiles exhibited a low thermal conductivity(~34 mW/(m·K))and outstanding thermal insulation properties under a wide range of *** addition,surface modification by Teflon resin could make the ANAFs hydrophobic,thus exhibiting their applicational pros-pects in a humid ***,the aramid nanofiber-based aerogel fibers and their textile throw light in a favorable direction for developing high-performance thermal insulation fibers and textiles.

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