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Isolation and Identification of Flavonoids Found in Zostera marina Collected in Norwegian Coastal Waters

Isolation and Identification of Flavonoids Found in Zostera marina Collected in Norwegian Coastal Waters

作     者:Kjersti Hasle Enerstvedt Monica Jordheim Øyvind M. Andersen Kjersti Hasle Enerstvedt;Monica Jordheim;Øyvind M. Andersen

作者机构:Department of Chemistry University of Bergen Bergen Norway 

出 版 物:《American Journal of Plant Sciences》 (美国植物学期刊(英文))

年 卷 期:2016年第7卷第7期

页      面:1163-1172页

学科分类:1008[医学-中药学(可授医学、理学学位)] 1006[医学-中西医结合] 100602[医学-中西医结合临床] 10[医学] 

主  题:Zostera marina Sulphated Flavones NMR Spectral Data Characterization Stability 

摘      要:In extracts of the seagrass Zostera marina, collected in coastal waters of West-Norway, fourteen different flavones and high amounts of rosmarinic acid were identified. Five of the flavones were found to be sulphated, among these were luteolin 7,3 -disulphate and chrysoeriol 7-sulphate structures previously not published with complete NMR assignments. Luteolin 7-O-β-(6 -malonyl) glucoside, and two other malonylated flavone compounds occurring in trace amounts, were identified for the first time in Z. marina. The sulphated flavones were fairly stable in slightly acidified (0.1% trifluoroacetic acid) extracts stored for months, however, under more acidic conditions (0.5% trifluoroacetic acid in the extracts) they were susceptible to undergo hydrolyses. When the solvents of purified fractions were removed by rotary evaporation, the sulphated flavones quickly decomposed to their corresponding aglycones due to the increased acid concentrations.

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