Influence of carbonization temperature on cobalt-based nitrogendoped carbon nanopolyhedra derived from ZIF-67 for nonoxidative propane dehydrogenation

作     者：Yu-Ming Li Zi-Ye Liu Qi-Yang Zhang Ya-Jun Wang Guo-Qing Cui Zhen Zhao Chun-Ming Xu Gui-Yuan Jiang 

作者机构：State Key Laboratory of Heavy Oil ProcessingChina University of PetroleumBeijing102249China 

出 版 物：《Petroleum Science》 (石油科学（英文版）)

年 卷 期：2023年第20卷第1期

页      面：559-568页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：This work is supported by the National Natural Science Foundation of China(Grant Nos.21802167,21961132026,92034302,21878331,91645108) the National Key Research and Development Program Nanotechnology Specific Project(No.2020YFA0210903) 

主　　题：Propane dehydrogenation ZIF-67 Nitrogen-doped carbon Cobalt 

摘      要：Propylene is a significant basic material for petrochemicals such as polypropylene,propylene oxide,*** abundant propane supply from shale gas,propane dehydrogenation(PDH)becomes extensively attractive as an on-purpose propylene production route in recent ***-doped carbon(NC)nanopolyhedra supported cobalt catalysts were synthesized in one-step of ZIF-67 pyrolysis and investigated further in ***,TEM and N_(2) adsorption-desorption were used to study the influence of carbonization temperature on as-prepared NC supported cobalt *** temperature is found to affect the cobalt phase and nitrogen species of the *** the positive correlation was established between Co0 proportion and space time yield of propylene,indicating that the modulation of carbonization temperature could be important for catalytic performance.