Tunable ultrathin dual-phase P-doped Bi_(2)MoO_(6) nanosheets for advanced lithium and sodium storage
作者机构:Centre for Advanced Structural MaterialsCity University of Hong Kong Shenzhen Research InstituteGreater Bay Joint DivisionShenyang National Laboratory for Materials ScienceShenzhen 518057China Hong Kong Branch of National Precious Metals Material Engineering Research CentreCity University of Hong KongKowloonHong KongChina School of Materials Science and EngineeringSoutheast UniversityNanjing 211189China School of ScienceHarbin Institute of TechnologyShenzhen 518055China Department of Mechanical EngineeringCity University of Hong KongKowloonHong KongChina CityU-Shenzhen Futian Research InstituteShenzhen 518045China Center of Super-Diamond and Advanced Films(COSDAF)City University of Hong KongKowloonHong KongChina Department of Material Science and EngineeringCity University of Hong KongKowloonHong KongChina
出 版 物:《Nano Research》 (纳米研究(英文版))
年 卷 期:2022年第15卷第7期
页 面:6128-6137页
核心收录:
学科分类:080801[工学-电机与电器] 0808[工学-电气工程] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学]
基 金:supported by Shenzhen-Hong Kong Science and Technology Innovation Cooperation Zone Shenzhen Park Project:HZQB-KCZYB-2020030 the National Key R&D Program of China(Project No.2017YFA0204403) Hong Kong Innovation and Technology Commission via the Hong Kong Branch of National Precious Metals Material Engineering Research Center
主 题:amorphous/nanocrystalline dual-phase structure ultrathin nanosheets P-doped Bi_(2)MoO_(6) anode materials lithium-ion batteries sodium-ion batteries
摘 要:The construction of electrode materials for lithium-ion batteries(LIBs)and sodium-ion batteries(SIBs)has gradually been an appealing and attractive technology in energy storage research *** the present work,a facile strategy of synthesizing ultrathin amorphous/nanocrystal dual-phase P-doped Bi_(2)MoO_(6)(denoted as P-BiMO)nanosheets via a one-step wet-chemical synthesis approach is *** distinct from conventional two-dimensional(2D)nanosheets,our newly developed ultrathin P-BiMO nanosheets exhibit a unique tunable amorphous/nanocrystalline dual-phase structure with several compelling advantages including fast ion exchange ability and superb volume change buffer *** experimental results reveal that our prepared P-BiMO-6 electrode delivers an excellent reversible capacity of 509.6 mA·g^(−1) after continuous 1,500 cycles at the current densities of 1,500 mA·g^(−1) and improved rate performance for *** the meanwhile,the P-BiMO-6 electrode also shows a reversible capacity of 300.6 mA·g^(−1) after 100 cycles at 50 mA·g^(−1) when being used as the SIBs *** present work uncovers an effective dual-phase nanosheet structure to improve the performance of batteries,providing an attractive paradigm to develop superior electrode materials.