Carbohydrate-derived porous carbon materials:An ideal platform for green organic synthesis
Carbohydrate-derived porous carbon materials: An ideal platform for green organic synthesis作者机构:School of Food Science and Pharmaceutical EngineeringNanjing Normal UniversityNanjing 210023China School of Pharmaceutical SciencesNanjing Tech UniversityNanjing 210009China School of Chemical EngineeringNanjing University of Science and TechnologyNanjing 210094China
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2022年第33卷第1期
页 面:186-196页
核心收录:
学科分类:081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0703[理学-化学]
基 金:supported by the National Key Research and Development Project(No.2021YFC2100100) National Natural Science Foundation of China(Nos.32001266,22007049) Natural Science Foundation of Jiangsu Province(No.BK20200728)。
主 题:Carbohydrates Carbon materials Green chemistry Catalysis Organic synthesis
摘 要:Porous carbon materials have attracted much attention in the field of organic synthesis in recent years,due to their tunable properties,excellent catalytic activity and stability.Biomass-based carbohydrates emerge as an ideal precursor for the generation of these materials owing to their renewability,low cost,non-toxicity and high content of functional groups.Thus,carbon materials prepared from carbohydrates is of considerable importance for the sustainable development of organic chemistry.The present review not only summarizes recent examples of carbohydrate-derived porous carbon material-catalyzed organic reactions including the oxidation,hydrogenation,cross-coupling,esterification and condensation reactions,but also introduces the preparation and functionalization strategies of these materials.Furthermore,the challenges and opportunities of organic synthesis over these sustainable materials have also been addressed.This review will stimulate further research on exploring novel carbohydrate-derived porous carbon materials and new sustainable organic synthetic processes over these materials.