Hydrate formation from liquid CO_(2) in a glass beads bed

作     者：Nan Li Jing-Yu Kan Chang-Yu Sun Guang-Jin Chen Nan Li;Jing-Yu Kan;Chang-Yu Sun;Guang-Jin Chen

作者机构：State Key Laboratory of Heavy Oil ProcessingChina University of Petroleum-Beijing at KaramayKaramay 834000China State Key Laboratory of Heavy Oil ProcessingChina University of PetroleumBeijing 102249China 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2022年第35卷第3期

页      面：185-191页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China(No.22008258) Tianshan Youth Program in Xinjiang Uygur Autonomous Region(2019Q089) the Scientific Research Program of Universities in Xinjiang Uygur Autonomous Region(XJEDU2019Y069) 

主　　题：Liquid CO_(2) Hydrate formation Sequestration Kinetic Water conversion 

摘      要：CO_(2)sequestration in marine sediments as solid hydrates is a potential way to capture and store anthropogenic CO_(2).In this study,hydrate formation from liquid CO_(2)in marine sediments was simulated in a glass beads bed,and the factors affecting the kinetics of hydrate formation were *** results indicated that the rapid initial hydrate formation with a high driving force always increases the mass transfer resistance,which slows down hydrate *** final ratio of water conversion is higher under conditions of low temperature and higher pressure.A smaller particle size is conductive to initial CO_(2)hydrate growth,but the water conversion ratio in a bed with larger particles is slightly *** with other factors,the change in water saturation has an obvious effect on the final water *** inhibit the initial hydrate formation during the injection process,in this paper,a kinetic inhibitor is proposed for pre-injection into marine *** work shows that at a low pressure,a lowconcentration inhibitor has an obvious inhibition effect on hydrate ***,at a high pressure,it is necessary to increase the concentration of inhibitor to produce an obvious inhibition effect.