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Novel Poly(methyl methacrylate)-based Ionomers Used as Multifunctional Aids to Modify Poly(vinyl chloride)

Novel Poly(methyl methacrylate)-based Ionomers Used as Multifunctional Aids to Modify Poly(vinyl chloride)

作     者:Li-na Zhang 宋义虎 郑强 

作者机构:Department of Polymer Science and Engineering Zhejiang University Hangzhou 310027 China MOE Key Laboratory of Macromolecular Synthesis and Functionalization Zhejiang University Hangzhou 310027 China 

出 版 物:《Chinese Journal of Polymer Science》 (高分子科学(英文版))

年 卷 期:2016年第34卷第4期

页      面:483-490页

核心收录:

学科分类:0817[工学-化学工程与技术] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0703[理学-化学] 

主  题:Rigid PVC Ionomers Thermal stability Plasticization Multifunction. 

摘      要:Poly(methyl methacrylate) (PMMA) based ionomers with different lanthanum (La(III)) contents (PMMA-XLa) synthesized by free radical solution polymerization were applied to poly(vinyl chloride) (PVC) resins as a kind of multifunctional aids, and their performances were evaluated by measuring the static stability time, initial discoloration, transparency, fusion behavior and tensile strength of the modified PVC. The ionomers with proper lanthanum (La(III)) contents show a better thermal stability efficiency in comparison with traditional stabilizer lanthanum stearate. Meantime, they can accelerate PVC plasticization more efficiently than PMMA. The rigid PVC products stabilized with the ionomers present good transparency and enhanced tensile strength.

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