THE STEREOSTRUCTURAL INVESTIGATION OF 3(R), 8-DIMETHYL-2(R), 5-BIS(1-METHYL-ETHYL)-6-OXO-2, 3, 6, 7, 9, 10-HEXAHYDRO-1H-3A, 7- ETHANOAZULENE-10-CARBONITRILE BY 2-D NMR SPECTROSCOPY
THE STEREOSTRUCTURAL INVESTIGATION OF 3(R), 8-DIMETHYL-2(R), 5-BIS(1-METHYL-ETHYL)-6-OXO-2, 3, 6, 7, 9, 10-HEXAHYDRO-1H-3A, 7- ETHANOAZULENE-10-CARBONITRILE BY 2-D NMR SPECTROSCOPY作者机构:Dalian Institute of Chemical Physics Academia Sinica Dalian 116012 PRC Spectrospin AG Zürich
出 版 物:《Chinese Science Bulletin》 (科学通报(英文版))
年 卷 期:1990年第35卷第12期
页 面:997-1002页
核心收录:
主 题:phase-sensitive COSY NOESY long-range C-H chemical shift correlation spectra BIRD pulses.
摘 要:A novel alkaloid compound with efficacious antihypertension activity was synthesized from one of heptatrienyl derivatives which was obtainod from curcumol by GUO Yong-tian et al. The structural determination of crystalline intermediate is very important for the structural elucidation of final reductive product and for designing and synthesizing