Asymmetric catalytic nitrooxylation and azidation of β-keto amides/esters with hypervalent iodine reagents

作     者：Changqiang He Zhikun Wu Yuqiao Zhou Weidi Cao Xiaoming Feng 

作者机构：Key laboratory of Green Chemistry&TechnologyMinistry of EducationCollege of ChemistrySichuan UniversityChengdu 610064China 

出 版 物：《Organic Chemistry Frontiers》 (有机化学前沿（英文）)

年 卷 期：2022年第9卷第3期

页      面：703-708页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：We appreciate the National Natural Science Foundation of China(22071160)for financial support 

主　　题：conditions esters iodine 

摘      要：Chiral Lewis acid-catalyzed enantioselective nitrooxylation of cyclic and acyclicβ-keto amides/esters with hypervalent iodine(III)reagents is reported.A number ofα-nitrooxy-β-keto amides/esters were obtained with good yields and high enantioselectivities by using bench-stable nitratobenziodoxole under mild conditions.