Novel aluminum-based fuel:Facile preparation to improve thermal reactions

作     者：Fa-yang Guan Hui Ren Wan-jun Zhao Xin-zhou Wu Qing-jie Jiao Fa-yang Guan;Hui Ren;Wan-jun Zhao;Xin-zhou Wu;Qing-jie Jiao

作者机构：State Key Laboratory of Explosion Science and TechnologyBeijing Institute of TechnologyBeijing100081China 

出 版 物：《Defence Technology（防务技术）》 (Defence Technology)

年 卷 期：2022年第18卷第10期

页      面：1852-1862页

核心收录：

学科分类：0806[工学-冶金工程] 0817[工学-化学工程与技术] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 0802[工学-机械工程] 0701[理学-数学] 0801[工学-力学（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：supported by National Natural Science Foundation of China[No.21975024] 

主　　题：Aluminum-based fuel Heterogeneous nucleation Molecular dynamics simulation Thermal reaction High energy laser-induced shockwave experiment 

摘      要：To improve the thermal properties of aluminum(Al)in the energetic system,a coated structure with ammonium perchlorate(AP)was prepared by a facile *** N,N-Dimethylformamide(DMF)was chosen as an ideal solvent based on heterogeneous nucleation theory and molecular dynamics *** coated structure could enlarge the contact area and improve the reaction environment to enhance the thermal *** addition of AP could accelerate oxidation temperature of Al with around 17.5°*** the heat release of 85@15 composition rises to 26.13 k J/g and the reaction degree is97.6%with higher peak pressure(254.6 k Pa)and rise rate(1.397 MPa/s).An ideal ratio with 15 wt%AP was probed *** high energy laser-induced shockwave experiment was utilized to simulate the reaction behavior in hot *** the larger activated mixture of coated powder could release more energy to promote the growth of shockwave with higher speed up to 518.7±55.9 m/*** conclusion,85@15 composition is expected to be applied in energetic system as a novel metal fuel.