Recent progress in advanced core-shell metal-based catalysts for electrochemical carbon dioxide reduction

作     者：Fengqi Wang Wenlong Zhang Hongbin Wan Chenxi Li Wankai An Xia Sheng Xiaoyu Liang Xiaopeng Wang Yunlai Ren Xin Zheng Dongcan Lv Yuchen Qin Fengqi Wang;Wenlong Zhang;Hongbin Wan;Chenxi Li;Wankai An;Xia Sheng;Xiaoyu Liang;Xiaopeng Wang;Yunlai Ren;Xin Zheng;Dongcan Lv;Yuchen Qin

作者机构：College of SciencesHenan Agricultural UniversityZhengzhou 450000China Oilfield Technology Research Institute of Fengcheng Oilfield Operation AreaXinjiang Oilfield CompanyKaramay 834000China College of Life ScienceChongqing Normal UniversityChongqing 401331China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2022年第33卷第5期

页      面：2259-2269页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：funded by the National Natural Science Foundation of China (Nos. 21706074 and 21972038) the Natural Science Foundation of Henan Province (No. 2023000410209) the Key Research and Promotion Project of Henan Province (Nos. 202102210261 and 202102310267) the Top-notch Personnel Fund of Henan Agricultural University (No. 30500682) The Science and Technology Research Program of Chongqing Municipal Education Commission (No. KJQN202000519) the foundation project of Chongqing Normal University (No. 18XLB008) 

主　　题：CMCs Electrochemical CO_(2)RR Tandem catalysis Lattice strain effect Defect engineering 

摘      要：Electrochemical carbon dioxide reduction(CO_(2)RR)plays an important role in solving the problem of high concentration of CO_(2)in the atmosphere and realizing carbon ***-shell structure has many unique features including tandem catalysis,lattice strain effect,defect engineering,which exhibit great potential in *** this review,we focus on the advanced core-shell metal-based catalysts(CMCs)for electrochemical CO_(2)*** recent progress of CMCs in electrocatalytic CO_(2)RR is described as the follow-ing aspects:(1)The mechanism of electrochemical CO_(2)RR and evaluation parameters of electrocatalyst performance,(2)preparation methods of core-shell metal catalysts and core-shell structural advantages and(3)advanced CMCs towards electrochemical CO_(2)***,we make a brief conclusion and propose the opportunities and challenges in the field of electrochemical CO_(2)RR.