Synthesis and luminescence of ultrasmall CsPbBr_(3) nanocrystals and CsPbBr_(3)/Cs_(4)PbBr_(6) composites by one-pot method

作     者：Xi-Bing Li Wen-Tao Huang Rui-Rong Zhang Yue Guo Hui-Jie Yang Xiao-Yue He Ming-Xun Yu Li-Xi Wang Qi-Tu Zhang Xi-Bing Li;Wen-Tao Huang;Rui-Rong Zhang;Yue Guo;Hui-Jie Yang;Xiao-Yue He;Ming-Xun Yu;Li-Xi Wang;Qi-Tu Zhang

作者机构：College of Materials Science and EngineeringNanjing Tech UniversityNanjing 210009China Jiangsu Collaborative Innovation Center for Advanced Inorganic Function CompositesNanjing 210009China Institute of Non-Metallic MaterialsJi'nan 250031China College of 2011Nanjing Tech UniversityNanjing 210009China 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：2022年第41卷第4期

页      面：1230-1238页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：the National Frontier Technology Key R&D Project(Nos.XXX-125 and JXXX-2019-058) the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD) the Collaborative Innovation Center of Advanced Inorganic Functional Composites of Jiangsu Province 

主　　题：composites (3) method 

摘      要：All-inorganic perovskites CsPbX_(3)(X=Cl,Br,I)have attracted worldwide interest due to their excellent lumi-nescent ***,Cs_(4)PbBr_(6) have been studied because they can enhance the luminescent efficiency and stability of CsPbBr_(3).Herein,we introduced a microfluidic method based on room-temperature supersat-urated recrystallization to synthesize blue-emitting CsPbBr_(3)nanocrystals(NCs)and green-emitting CsPbBr_(3)/Cs_(4)PbBr_(6)*** ultrasmall CsPbBr_(3)NCs emitted at a deep blue wavelength of 461 nm with the full width at half maximum(FWHM)of 15 *** electron microscopy(TEM)results demonstrated that ultrasmall CsPbBr_(3)NCs with the average particle size of 3.8 nm were synthesized and the CsPbBr_(3)NCs were crystallized as monoclinic structure.