Kinetics and fractionation of hydrogen isotopes during gas formation from representative functional groups

作     者：Shuang-Fang Lu Guo-Qi Feng Ming-Li Shao Ji-Jun Li Hai-Tao Xue Min Wang Fang-Wen Chen Wen-Biao Li Xiao-Ting Pang Shuang-Fang Lu;Guo-Qi Feng;Ming-Li Shao;Ji-Jun Li;Hai-Tao Xue;Min Wang;Fang-Wen Chen;Wen-Biao Li;Xiao-Ting Pang

作者机构：aResearch Institute of Unconventional Oil&Gas and New EnergyChina University of PetroleumQingdaoShandong 266580China Exploitation and Development Research Institude of Jilin Oilfield CompanyCNPCSongyuanJilin138000China 

出 版 物：《Petroleum Science》 (石油科学（英文版）)

年 卷 期：2021年第18卷第4期

页      面：1021-1032页

核心收录：

学科分类：0820[工学-石油与天然气工程] 081803[工学-地质工程] 08[工学] 0818[工学-地质资源与地质工程] 

基　　金：the National Natural Science Foundation of China(41672130,41772131) the National Oil and Gas Major Project(2016ZX05061-003-001,2016ZX05029002-002) the Sinopec Scientific and Technological Research Project(P17027-3) the Ministry of Education’s Independent Innovation Fund Project(14CX02224A)for financial support of this study。 

主　　题：Gas-forming compounds Pyrolysis Hydrogen isotopes Fractionation Chemical kinetics 

摘      要：A gold tube simulation device was used to study the cleavage of representative compounds into gas.The goal of this study is to investigate hydrogen isotope composition change of gaseous hydrocarbons during maturity.Gas chromatography and isotopic analyses were conducted to determine how the yield of natural gas components and their hydrogen isotopic composition were related to experimental temperature and heating rate.A chemical kinetic model for the generation of each component of the natural gas and for the hydrogen isotopic fractionation was established and calibrated based on the results.Results indicate that the hydrogen isotopic fractionation during the evolution of various gas-forming organic materials can be satisfactorily described by chemical kinetic models.During regular methane generation,the reactions at low-activation-energy region had a greater contribution than the high-activation-energy region.While the reactions with high-activation-energy region had greater contribution of deuterium-rich methane.Compared with carbon isotope fractionation,this results in a greater hydrogen isotopic fractionation,which is more sensitive to changes in maturity.This study lays a foundation for further investigations of genesis and maturity of natural gas provided by hydrogen isotopic fractionation.It also provides fundamental knowledge for investigating the filling history of natural gas reservoir and for identifying.