Strong coupling with absorption and emission features of Ag@Au hollow nanoshells interacting with J-aggregated dye molecules
与聚集 J 的染料分子交往的 Ag@Au 空 nanoshells 的强壮的结合吸收和排放特征作者机构:State Key Laboratory of Precision SpectroscopyEast China Normal UniversityShanghai 200241China Collaborative Innovation Center of Extreme OpticsShanxi
出 版 物:《Chinese Optics Letters》 (中国光学快报(英文版))
年 卷 期:2021年第19卷第12期
页 面:137-142页
核心收录:
学科分类:07[理学] 070205[理学-凝聚态物理] 08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0702[理学-物理学]
基 金:supported by the National Key R&D Program of China(No.2017YFA0303403) the National Natural Science Foundation of China(Nos.11874015,12074012,11674099 11722431) the Shanghai International CooperationProject(No.16520710600) the Program of Introducing Talents of Discipline to Universities(No.B12024)
主 题:surface plasmon nanoshells plasmon-exciton coupling Rabi splitting
摘 要:We investigate the strong coupling from 5,5’,6,6’-tetrachloro-1,1’-diethyl-3,3’-di(4-sulfobutyl)-benzimidazolocarbocyanine(TDBC)molecules near pure nano-triangular Ag prisms or Ag@Au hollow *** TDBC molecules are deposited on pure Ag nanoprisms or Ag@Au hollow nanoshells with the plasmonic resonance peak,matching very closely with the absorption band of TDBC J-aggregates,obvious Rabi splitting can be observed due to the strong coupling ***,the photoluminescence intensity decreased with the increasing of the temperature,verifying the decreasing plasmon-exciton coupling interaction in the higher *** experimental results are coincident with the simulation results calculated by finite-difference time-domain method.