Roles of metal element substitutions from the bimetallic solid state electrolytes in lithium batteries
作者机构：State Key Laboratory of Separation Membranes and Membrane ProcessesNational Center for International Joint Research on Separation MembranesTiangong UniversityTianjin 300387China School of Textile Science and EngineeringTiangong UniversityTianjin 300387China
出 版 物：《Particuology》 (颗粒学报（英文版）)
年 卷 期：2022年第20卷第6期
页 面：51-71页
核心收录：
学科分类：0808[工学-电气工程] 0817[工学-化学工程与技术] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 0702[理学-物理学]
基 金：This work was supported by the National Natural Science Foundation of China(grant No.51973157) the Special Grade of the Financial Support from the China Postdoctoral Science Foundation(grant No.2020T130469) Tianjin Municipal University Students'Innovation and Entrepreneurship Training Program Project(grant No.201910058036) the Science and Technology Plans of Tianjin(grant No.19PTSYJCO0010) the Science&Technology Development Fund of Tianjin Education Commission for Higher Education(grantNo.2018KJ196) State Key Laboratory of Membrane and Membrane Separation,Tiangong University
主 题：Metal element substitutions Bimetallic inorganic particles Solid-state electrolytes All-solid-state lithium batteries Mechanisms
摘 要：All-solid-state lithium batteries(ASSLBs),receiving extensive attentions and studies,exhibit better safety,environmental friendliness,stability,wider electrochemical stability window and higher energy density than traditionally liquid lithium *** a variety of inorganic materials,with highly replaceable,the non-lithium metal elements emerge in endlessly and affect performances in diversiform *** to facile preparation,convertible structures and excellent properties,the lithium-containing bimetallic granular materials are often applied as important components of electrolytes in lithium *** this review,in terms of the properties of substituted elements,changing crystal structures,increasing vacancies or defects and improving the interfacial conductions,the roles of metal element substitutions of inorganic particles on the improvement of solid-state electrolytes are *** the applications of substituted strategies in ASSLBs as the host of inorganic particles electrolytes and as fillers or modifications for composite electrolytes are also investigated and *** also summarizes the current concerns and obstacles that need to be broken through,as well as provides a basis guide for the selection and optimization of inorganic particles.
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