The emerging applications of pillararene architectures in supramolecular catalysis

作     者：Kaiya Wang Xueqi Tian Jacobs H.Jordan Krishnasamy Velmurugan Leyong Wang Xiao-Yu Hu Kaiya Wang;Xueqi Tian;Jacobs H.Jordan;Krishnasamy Velmurugan;Leyong Wang;Xiao-Yu Hu

作者机构：College of Materials Science and TechnologyNanjing University of Aeronautics and AstronauticsNanjing 211106China The Southern Regional Research CenterAgricultural Research ServiceUSDANew OrleansLA 70124United States Key Laboratory of Mesoscopic Chemistry of MOESchool of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2022年第33卷第1期

页      面：89-96页

核心收录：

学科分类：07[理学] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the Natural Science Foundation of Jiangsu Province(No.BK20200432) National Natural Science Foundation of China for Sino-German Mobility Program(No.M-0411) the Fundamental Research Funds for the Central Universities(Nos.NE2019002 and NS2021040)。 

主　　题：Supramolecular catalysis Host–guest chemistry Macrocycles Pillararene Self-assembly 

摘      要：Over the last decade,numerous research efforts have been devoted to pillar[n]arenes since their debut.The popularity of pillararenes is a reflection of current research trend in supramolecular and macrocyclic chemistry in general.Among the vast applications(such as chemosensors,drug delivery,transmembrance channels,and separation)of pillararenes,their utilization in catalysis is a relatively less explored area.However,soaring attention has been paid by researchers in recent years and this field has seen gradual increasing publications.Therefore,in this review we will discuss progress in the emerging applications of pillararene architectures in catalysis based on various reaction genre including reduction,oxidation,coupling,decomposition and others.Furthermore,this review not only focuses on the pillararenes based current progress in catalysis,but also provides the signs for future development in this research field.