Unprecede nted tunable hydrophobic effect and anion recognition triggered by AIE with Hofmeister series in water
Unprecedented tunable hydrophobic effect and anion recognition triggered by AIE with Hofmeister series in water作者机构:Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou ProvinceGuizhou UniversityGuiyang 550025China
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2021年第32卷第5期
页 面:1679-1682页
核心收录:
学科分类:07[理学] 070304[理学-物理化学(含∶化学物理)] 0703[理学-化学]
基 金:This work was supported by the National Natural Science Foundation of China(No.21871063) Guizhou University(No.YJSCXJH(2019)012).
主 题:AIE Anion binding Hofmeister series Hydrophobic effect Self-assembly
摘 要:An un precedented tun able hydrophobic effect in self-assembly of a small cationic organic fluorophore(NI-TPy^(+))-based with aggregation-induced emission(AIE)property was realized in aqueous solution.The amplification of hydrophobicity was found to be significantly dependent upon the increasing aggregates of NI-TPy^(+),which enabled the study of the hydrophobic binding of chaotropic anions with the Hofmeister series.