Study on the Inert Coordination Compound in the System of“Molybdenum(Ⅵ)—TAE—Hydroxylamine”and its Analytical Application

作     者：Chen Huaxu Shao Guangdi Department of Chemistry,University of Science and Technology BeijingBai Linshan Department of Chemical Engineering,East China Institute of Metallurgy 

出 版 物：《Rare Metals》 (稀有金属（英文版）)

年 卷 期：1989年第9卷第2期

页      面：58-63页

核心收录：

学科分类：08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

主　　题：and its Analytical Application Molybdenum Hydroxylamine Study on the Inert Coordination Compound in the System of TAE 

摘      要：In the presence of ethyl alcohol or emulsifier OP,molybdenum(Ⅵ) forms 1∶1∶1 water soluble colored coordination com- pound with both of 2-(2-thiazolylazo)-5-diethylaminophenol (abbreviation TAE) and *** deep blue coordination compound is inert characteristically and remains stable in 1.7 mol/L sulfuric acid,2.4 mol/L hydrochloric or ni- tric *** will not be decomposed by masking agents even on boiled,while in that case,almost all the colored coordination com- pounds formed by other metal ions will be decomposed *** inert character of the coordination compound of molybdenum(Ⅵ) and its utilization in improving the analytical selectivity have been *** the coexistence of various for- eign ions,especially in the presence of a great quantity of tungsten,which always interferes with the determination of molybdenum,the direct determination of molybdenum in the aqueous solution by applying this system has shown an acceptable sensitivity and *** the results of determination in some synthetic and standard samples,it seems feasible to use this system in the determination of molybdenum in nonferrous alloys.