Polyoxometalates-based heterogeneous catalysts in acid catalysis

作     者：Lifei Lian Huaiying Zhang Sai An Wei Chen Yu-Fei Song Lifei Lian;Huaiying Zhang;Sai An;Wei Chen;Yu-Fei Song

作者机构：State Key Laboratory of Chemical Resource EngineeringBeijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2021年第64卷第7期

页      面：1117-1130页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：supported by the National Natural Nature Science Foundation of China(U1707603,21625101,21521005,21808011,U1507102) the National Key Research and Development Program of China(2017YFB0307303) Beijing Natural Science Foundation(2182047,2202039) the Fundamental Research Funds for the Central Universities(XK1802-6,XK1803-05,XK1902,12060093063) 

主　　题：polyoxometalates solid acid catalyst acid catalysis heterogeneous catalysis esterification 

摘      要：Acid catalysis,one of the most important industrial processes,suffers from the toxicity,corrosion and recyclability problems of conventional homogeneous acid ***,the development of green heterogeneous acid catalysts becomes the focus of fundamental research and industrial *** a class of discrete anionic metal-oxygen clusters with tunable structure at the molecular and atomic scales,polyoxometalates(POMs)benefit from their super strong Br?nsted acidity,high proton mobility,and thermal ***-based heterogeneous catalysts have been used as the potential green alternatives to conventional homogeneous acid *** this review,we summarize recent progress on the design strategies of the POMs-based heterogeneous catalysts and their catalytic properties in acid-catalyzed reactions,where they are combined with functionalized cations,modified through covalent interactions,supported onto the non-precious metal support,and introduced into the framework of porous *** design,functional strategies and catalytic performance of these POMs-based heterogeneous catalysts in specific acid-catalyzed reactions are emphasized.