Solution and Solid-Phase Growth of Bulk Halide Perovskite Single Crystals
作者机构：Department of PhysicsShanghai Key Laboratory of Materials Protection ond Advanced Materials in Electric PowerShanghai University of Electric PowerShanghai 200090China
出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)
年 卷 期：2021年第39卷第5期
页 面：1353-1363页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：the National Natural Science Foundation of China(Grant No.61875119) the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning,Shanghai Rising-Star Program(Grant No.19QA1404000) Shanghai Talent Development Fund,and the "Chen Guang" project supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation(Grant No.18CG63)
主 题：Halide perovskite Bulk single crystal Crystal growth Synthetic methods Semiconductors
摘 要：Perovskite is a magic material with a structure similar to calcium titanate(CaTi03).Among perovskite materials,halide perovskite has gained considerable attention owing to its superior semiconducting properties such as direct band gap and relatively small effective mass of electrons and *** recent years,the power conversion efficiency of halide perovskite solar cells has been continuously *** growth of bulk halide perovskite single crystals(PSCs)has become crucial to the investigation of their intrinsic *** the entire preparation process,the growth method generally plays a significant role,which determines the quality and size of the target *** this review,we summarized the existing mainstream synthetic methods for growing bulk PSCs including solution and solid-phase *** discussed the characteristics of these methods and the influence of the growth parameters on the quality and size of the resulting ***,we briefly introduce the applications of PSCs as semiconductors in photodetectors and gas *** the growth behaviors of PSCs is insightful for future research on their synthesis and applications.
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