Nanostructured porous polyaniline(PANI)coated carbon cloth(CC)as electrodes for flexible supercapacitor device

作     者：Dinesh J.Ahirrao Ajay Kumar Pal Vikalp Singh Neetu Jha Dinesh J.Ahirrao;Ajay Kumar Pal;Vikalp Singh;Neetu Jha

作者机构：Department of PhysicsInstitute of Chemical TechnologyMatunga(E)Mumbai400019India Department of PhysicsRamniranjan Jhunjhunwala CollegeGhatkopar(W)Mumbai 400086India 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：2021年第88卷第29期

页      面：168-182页

核心收录：

学科分类：080801[工学-电机与电器] 0808[工学-电气工程] 0817[工学-化学工程与技术] 0806[工学-冶金工程] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 0802[工学-机械工程] 0801[工学-力学（可授工学、理学学位）] 0702[理学-物理学] 

基　　金：the research grant obtained from the Government of India,Under the DST-Nanomission program(No.SR/NM/NS-1110/2012) the DST-Inspire program(IFA12-PH-33) 

主　　题：Polyaniline Carbon cloth Flexible supercapacitor Flexible electrode Composite 

摘      要：Nanostructured porous polyaniline(PANI)has been synthesized and coated simultaneously on a highly flexible and conductive carbon cloth(CC)substrate using a simple in-situ chemical oxidative polymerization *** coated CC(PANI-CC)based flexible electrodes were further used for the fabrication of flexible supercapacitor *** the comparison purpose,pure PANI has also been synthesized and tested for its electrochemical *** energy storage capacity of PANI and PANI–CC composite was investigated using electrochemical techniques like CV,GCD,and EIS in a potential range from 0 to 0.8 V in 1 M H_(2)SO_(4)***-CC flexible electrodes exhibited the highest specific capacitance of 691 F/g;whereas,pure PANI could only achieve 575 F/g of specific capacitance at 1 A/*** also exhibited outstanding cyclic stability by recollecting 94%of its initial capacitance after 2000 GCD *** actual implementation,a flexible supercapacitor device has been fabricated using stainless steel sheets and PANI-CC flexile *** energy storage performance of the PANI-CC flexible supercapacitor device was tested at several bending angles,which resulted in 72%of capacitance retention at a maximum bending angle of 140°compared to the capacitance obtained at an angle 0°(flat state).PANI-CC exhibited improved electrochemical performance than pure PANI due to the synergistic effect between PANI and ***,CC helped in enhancing the conductivity and stability;whereas,PANI boosted the capacitance owing to its excellent porosity and fast pseudocapacitive charge storage response.