Ionic liquids for CO_(2) electrochemical reduction

作     者：Fangfang Li Francesca Mocci Xiangping Zhang Xiaoyan Ji Aatto Laaksonen Fangfang Li;Francesca Mocci;Xiangping Zhang;Xiaoyan Ji;Aatto Laaksonen

作者机构：Energy EngineeringDivision of Energy ScienceLuleåUniversity of TechnologyLuleå97187Sweden Department of Chemical and Geological SciencesUniversity of CagliariMonserrato 09042Italy CAS Key Laboratory of Green Process and EngineeringBeijing Key Laboratory of Ionic Liquids Clean ProcessState Key Laboratory of Multiphase Complex SystemsInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China Division of Physical ChemistryDepartment of Materials and Environmental ChemistryArrhenius LaboratoryStockholm UniversityStockholm 10691Sweden Center of Advanced Research in Bionanocojugates and Biopolymers“Petru Poni”Institute of Macromolecular ChemistryIasi 700469Romania State Key Laboratory of Materials-Oriented and Chemical EngineeringNanjing Tech UniversityNanjing 211816China 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2021年第34卷第3期

页      面：75-93页

核心收录：

学科分类：0710[理学-生物学] 083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 0817[工学-化学工程与技术] 08[工学] 070304[理学-物理化学(含∶化学物理)] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：F.Li and X.Ji thank the financial support from the Swedish Energy Agency(P47500-1) A.Laaksonen acknowledges the Swedish Research Council for financial support(2019-03865) partial support from a grant from Ministry of Research and Innovation of Romania(CNCS-UEFISCDI,project number PN-IIIP4-ID-PCCF-2016-0050,within PNCDI III) F.Mocci thanks the Fondazione di Sardegna,Project:“Precious metal-free complexes for catalytic CO2 reduction”(CUP:F71I17000170002)for the financial support 

主　　题：Carbon dioxide Ionic liquids Electro-reduction Electrolyte Electrocatalytic material Computer simulation 

摘      要：Electrochemical reduction of CO_(2) is a novel research field towards a CO_(2)-neutral global economy and combating fast accelerating and disastrous climate changes while finding new solutions to store renewable energy in value-added chemicals and *** liquids(ILs),as medium and catalysts(or supporting part of catalysts)have been given wide attention in the electrochemical CO_(2) reduction reaction(CO_(2) RR)due to their unique advantages in lowering overpotential and improving the product selectivity,as well as their designable and tunable *** this review,we have summarized the recent progress of CO_(2) electro-reduction in IL-based electrolytes to produce higher-value *** then have highlighted the unique enhancing effect of ILs on CO_(2) RR as templates,precursors,and surface functional moieties of electrocatalytic ***,computational chemistry tools utilized to understand how the ILs facilitate the CO_(2) RR or to propose the reaction mechanisms,generated intermediates and products have been discussed.