Synthesis of graphene materials by electrochemical exfoliation: Recent progress and future potential
作者机构:School of Chemical and Biomolecular EngineeringThe University of SydneySydneyNew South WalesAustralia Guangdong Provincial Key Laboratory of Microbial Culture Collection and ApplicationState Key Laboratory of Applied Microbiology Southern ChinaGuangdong Institute of MicrobiologyGuangdong Academy of SciencesGuangzhouChina
出 版 物:《Carbon Energy》 (碳能源(英文))
年 卷 期:2019年第1卷第2期
页 面:173-199页
核心收录:
学科分类:0830[工学-环境科学与工程(可授工学、理学、农学学位)] 08[工学] 0807[工学-动力工程及工程热物理] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0703[理学-化学] 0702[理学-物理学]
基 金:National Natural Science Foundation of China,Grant/Award Numbers:51678163,91851202 Australian Research Council,Grant/Award Number:FT160100107 and DP180102210
主 题:electrochemical exfoliation graphene graphene oxide graphite synthesis
摘 要:Synthesis of structurally controlled graphene materials is critical for realizing their practical *** electrochemical exfoliation of graphite has emerged as a simple method to produce graphene *** review examines research progress in the last 5 years,from 2015 to *** material synthesis methods generally have a trade‐off between increasing production yield and achieving better material property *** synthesis conditions for synthesizing pristine graphene,graphene oxide(GO),and graphene composites are significantly ***,in this review,we first discuss synthesis methods for graphene materials with high C/O ratios from four aspects:graphite electrodes,equipment engineering,electrolytes,and additional reduction ***,we survey synthesis methods for GO and examine how the pretreatment of the graphite electrodes,electrolytes,and operation parameters,such as applied voltages,electrolyte temperatures,and mechanical forces,affect the quality of ***,we summarize electrochemical exfoliation methods used to dope graphene materials,introduce covalent functional groups,incorporate various nanoparticles,and assembly of graphene *** all synthesis methods,we compare the properties of resulting graphene materials such as C/O ratios,lateral size,layer numbers,and quality characterized by Raman ***,we propose our perspectives on further *** hope this review stimulates more studies to realize the on‐demand production of graphene materials with desired properties using electrochemical exfoliation methods.