Plasma activation towards oxidized nanocarbons for efficient electrochemical synthesis of hydrogen peroxide

作     者：Wei CAI Yan WANG Changshan XIAO Haobin WU Xinyao YU 蔡伟;王燕;肖长山;吴浩斌;遇鑫遥

作者机构：School of Materials Science&EngineeringZhejiang UniversityHangzhou 310027People's Republic of China Institutes of Physical Science and Information TechnologyAnhui UniversityHefei 230601People's Republic of China Wendian CollegeAnhui UniversityHefei 230601People's Republic of China 不详 

出 版 物：《Plasma Science and Technology》 (等离子体科学和技术（英文版）)

年 卷 期：2021年第23卷第2期

页      面：38-46页

核心收录：

学科分类：081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：National Natural Science Foundation of China(No.12075002) the Outstanding Youth Fund of Anhui Province(No.2008085J21) the Anhui Provincial Supporting Program for Excellent Young Talents in Universities(No.gxyqZD2019005) the Innovation and Entrepreneurship Project of Overseas Returnees in Anhui Province(No.2019LCX018) 

主　　题：plasma activation hydrogen peroxide nanocarbon defect oxygen functional groups 

摘      要：Oxidized nanocarbons(ONCs)have been regarded as efficient electrocatalysts for H2O2 ***,wet chemical procedures involving large volumes of strong acid and long synthetic time are usually needed to obtain these ***,a plasma activation strategy is developed as a rapid and environmentally benign approach to obtain various ONCs,including oxidized multiwalled carbon nanotubes,single-walled carbon nanotube,graphene,and super P carbon *** a few minutes of plasma activation,oxygen-containing functional groups and defects can be effectively introduced onto the surface of *** electrocatalytic activity and selectivity are demonstrated by the plasma-ONCs for H2O2 *** oxidized multiwalled carbon nanotubes as an example,high selectivity(up to 95%)and activity(0.75 V at 1 mA cm^(−2))can be achieved in alkaline ***,ex situ x-ray photoelectron spectroscopy and in situ Raman measurements reveal that C–O,C=O,edge defect,and sp2 basal planar defect are probably the active sites.