Impact of environmental factors on the sampling rate ofβ-blockers and sulfonamides from water by a carbon nanotube-passive sampler
从由碳的水的 -blockers 和硫安类药剂的采样率上的环境因素的影响 nanotube 被动的刺绣花样作者机构:Department of Environmental AnalysisFaculty of ChemistryUniversity of Gdanskul.Wita Stwosza 63Gdansk 80-308Poland
出 版 物:《Journal of Environmental Sciences》 (环境科学学报(英文版))
年 卷 期:2021年第33卷第3期
页 面:413-427页
核心收录:
学科分类:082803[工学-农业生物环境与能源工程] 08[工学] 0828[工学-农业工程] 0804[工学-仪器科学与技术]
主 题:Carbon nanotubes Passive sampling Pharmaceuticals Sampling rates(R_s)
摘 要:Passive techniques are a constantly evolving approach to the long-term monitoring of micropollutants,including pharmaceuticals,in the aquatic *** paper presents,for the first time,the calibration results of a new CNTs-PSDs(carbon nanotubes used as a sorbent in passive sampling devices)with an examination of the effect of donor phase salinity,water pH and the concentration of dissolved humic acids(DHAs),using both ultrapure and environmental *** rates(R_(s))were determined for the developed kinetic *** has been observed that the impact of the examined environmental factors on the R_(s) values strictly depends on the type of the *** the case ofβ-blockers,the only environmental parameter affecting their uptake rate was the salinity of water.A certain relationship was noted,namely the higher the salt concentration in water,the lower the Rs values ofβ-*** the case of sulfonamides,water salinity,water pH 7-9 and DHAs concentration decreased the uptake rate of these compounds by *** determined Rs values differed in particular when the values obtained from the experiments carried out using ultrapure water and environmental waters were *** general conclusion is that the calibration of novel CNTs-PSDs should be carried out under physicochemical conditions of the aquatic phase that are similar to the environmental matrix.