Tuning the electronic structure of the earth-abundant electrocatalysts for oxygen evolution reaction(OER)to achieve efficient alkaline water splitting-A review

作     者：Mohammed-Ibrahim Jamesh Moussab Harb Mohammed-Ibrahim Jamesh;Moussab Harb

作者机构：Department of Physics and Materials ScienceCity University of Hong KongTat Chee AvenueKowloonHong KongChina Applied and Plasma PhysicsSchool of Physics(A28)University of SydneySydneyNSW 2006Australia KAUST Catalysis Center(KCC)Physical Sciences and Engineering Division(PSE)King Abdullah University of Science and Technology(KAUST)Thuwal 23955-6900Saudi Arabia 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2021年第30卷第5期

页      面：299-342页

核心收录：

学科分类：0820[工学-石油与天然气工程] 081702[工学-化学工艺] 0808[工学-电气工程] 081705[工学-工业催化] 0817[工学-化学工程与技术] 08[工学] 0807[工学-动力工程及工程热物理] 0827[工学-核科学与技术] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：supported by the King Abdullah University of Science and Technology(KAUST) 

主　　题：OER electrocatalyst Electrochemical water splitting Earth abundant electrocatalyst Hydrogen energy 

摘      要：Tuning the electronic structure of the electrocatalysts for oxygen evolution reaction(OER)is a promising way to achieve efficient alkaline water splitting for clean energy production(H2).At first,this paper introduces the significance of the tuning of electronic structure,where modifying the electronic structure of the electrocatalysts could generate active sites having optimal adsorption energy with OER intermediates,and that could diminish the energy barrier for OER,and that could improve the activity for ***,this paper reviews the tuning of electronic structure along with catalytic performances,synthetic methodologies,chemical properties,and DFT calculations on various nanostructured earth-abundant electrocatalysts for OER in alkaline ***,this review discusses the tuning of the electronic structure of the several nanostructured earth-abundant electrocatalysts including oxide,(oxy)hydroxide,layered double hydroxide,alloy,metal phosphide/phosphate,nitride,sulfide,selenide,carbon containing materials,MOF,core-shell/hetero/hollow structured materials,and materials with vacancies/defects for OER in alkaline environment(including activity:overpotential(η)of ≤200 mV at10 m A cm^(-2);stability:≥100 h;durability:≥5000 cycles).Then,this review discusses the robust stability of the electrocatalysts for OER towards practical ***,this review discusses the in situ formation of thin layer on the catalyst surface during *** addition,this review discusses the influence of the adsorption energy of the OER intermediates on OER performance of the ***,this review summarizes the various promising strategies for tuning the electronic structure of the electrocatalysts to achieve enhanced performance for OER in alkaline environment.