检索结果-南通市图书馆

Theoretical investigation of excited dipole bound states of alkali-containing diatomic anions

在线全文

学校读者我要写书评

暂无评论

Chinese physics B 2024年第5期33卷 389-393页

作者：连艺肖利丹边丽丽徐海峰闫冰 Institute of atomic and molecular physics Jilin UniversityChangchun 130012China

Information about electronic excited states of molecular anions plays an important role in investigating electron attachment and detachment *** we present a high-level theoretical study of the electronic structures of 12 alkali-metal-containing diatomic anions MX-(MX = LiH,LiF,LiCl,NaF,NaCl,NaBr,RbCl,KCl,KBr,RbI,KI and CsI).The equation-of-motion electron-attachment coupled-cluster singles and doubles(EOM-EA-CCSD) method is used to calculate the electron binding energies(EBEs) of 10 electronic excited states of each of the 12 molecule *** addition of different s-/p-/d-type diffusion functions in the basis set,we have identified possible excited dipole bound states(DBSs) of each *** the investigation of EBEs on the 12 MXs with dipole moment(DM) up to 12.1 D,we evaluate the dependence of the number of anionic excited DBSs on molecular *** results indicate that there are at least two or three DBSs of anions with a molecular DM larger than 7 D and a molecule with DM > 10 D can sustain a π-DBS of the *** study has some implications for the excited DBS electronic states of alkali-metal-containing diatomic molecules.

关键词： anions dipole bound states alkali-metal-containing diatomic molecules

Excitation and ionization of OCS molecules in strong UV and NIR laser fields

在线全文

学校读者我要写书评

暂无评论

Chinese physics B 2024年第7期33卷 285-291页

作者：师慧军刘洋孙添吕航徐海峰 Institute of atomic and molecular physics Jilin UniversityChangchun 130012China

Rydberg state excitation(RSE) is a highly non-linear physical phenomenon that is induced by the ionization of atoms or molecules in strong femtosecond laser fields. Here we observe that both parent and fragments(S, C, OC) of the triatomic molecule carbonyl sulfide(OCS) can survive strong 800 nm or 400 nm laser fields in high Rydberg states. The dependence of parent and fragment RSE yields on laser intensity and ellipticity is investigated in both laser fields, and the results are compared with those for strong-field ionization. Distinctly different tendencies for laser intensity and ellipticity are observed for fragment RSE compared with the corresponding ions. The mechanisms of RSE and strong-field ionization of OCS molecules in different laser fields are discussed based on the experimental results. Our study sheds some light on the strong-field excitation and ionization of molecules irradiated by femtosecond NIR and UV laser fields.

关键词： Rydberg state excitation strong field carbonyl sulfide ionization

Effect of sample temperature on femtosecond laser ablation of copper

在线全文

学校读者我要写书评

暂无评论

Chinese physics B 2024年第2期33卷 377-385页

作者：党伟杰陈雨桐陈安民金明星 Institute of atomic and molecular physics Jilin UniversityChangchun 130012China Jilin Provincial Key Laboratory of Applied atomic and molecular Spectroscopy Jilin UniversityChangchun 130012China

We conduct an experimental study supported by theoretical analysis of single laser ablating copper to investigate the interactions between laser and material at different sample temperatures,and predict the changes of ablation morphology and lattice *** investigating the effect of sample temperature on femtosecond laser processing,we conduct experiments on and simulate the thermal behavior of femtosecond laser irradiating copper by using a two-temperature *** simulation results show that both electron peak temperature and the relaxation time needed to reach equilibrium increase as initial sample temperature *** the sample temperature rises from 300 K to 600 K,the maximum lattice temperature of the copper surface increases by about 6500 K under femtosecond laser irradiation,and the ablation depth increases by 20%.The simulated ablation depths follow the same general trend as the experimental *** work provides some theoretical basis and technical support for developing femtosecond laser processing in the field of metal materials.

关键词： femtosecond laser two-temperature model sample temperature ablation depth

Direct Observation on H-Elimination Enhancement from C_(2)H_(4) through Non-Adiabatic Process by Femtosecond Laser Induced Coulomb Explosion

在线全文

学校读者我要写书评

暂无评论

Chinese physics Letters 2024年第5期41卷 17-22页

作者：金无维王春成赵晓戈杨译章任殿相刘泽槿李孝开罗嗣佐丁大军 Institute of atomic and molecular physics Jilin UniversityChangchun 130012China Jilin Provincial Key Laboratory of Applied atomic and molecular Spectroscopy Jilin UniversityChangchun 130012China

Ethylene, the simplest model of a carbon-carbon double bond system, is pivotal in numerous chemical and biological processes. By employing intense infrared laser pump-probe techniques alongside coincidence measurements, we investigate the ultrafast non-adiabatic dynamics involved in the breakage of carbon-carbon double bonds and hydrogen elimination in dissociation of ethylene. Our study entails analyzing the dynamic kinetic energy release spectra to assess three bond-breaking scenarios, movements of nuclei, and structural changes around the carbon atoms. This allows us to evaluate the relaxation dynamics and characteristics of various dissociative states. Notably, we observe a significant rise in the yield of fragments resulting from C–H bond breakage with the delay time extended, suggesting non-adiabatic coupling through conical intersections from C–C bond breakage as a probable cause.

关键词： pump Femto adiabatic

Low-energy inelastic electron scattering from carbon monoxide:Excitation and de-excitation of the X^(1)Σ^(+),a^(3)Π,a'^(3)∑^(+),A^(1)Π,d^(3)Δ,e^(3)∑^(-),I^(1)∑^(-)and D^(1)Δelectronic states

在线全文

学校读者我要写书评

暂无评论

Chinese physics B 2024年第4期33卷 444-450页

作者：卫鹏宇黄朝文程新路张红 Institute of atomic and molecular physics Sichuan UniversityChengdu 610065China College of physics Sichuan UniversityChengdu 610065China

Cross-sections for electronic excitation and de-excitation among the ground state and lowest-lying seven electronic excited states of carbon monoxide(CO)by low-energy electron impact are computed using the R-matrix *** excitation cross-sections from the ground state to the electronic states a^(3)Π,a'^(3)Σ^(+)+and A^(1)Πagree with previous experimental and theoretical *** addition,the cross-sections for the I^(1)Σ^(+)-and D^(1)Δstates of CO,which will cascade to CO a'^(3)Σ^(+)+and A^(1)Πstates,are ***,in contrast to the typical increase in electronic excitation cross-sections with collision energy,the de-excitation cross-sections show a negative trend with increasing energy.

关键词： electron-CO collision electronic excitation cross-sections R-matrix method

Theoretical investigation of electron-impact ionization of W8+ion

在线全文

学校读者我要写书评

暂无评论

Chinese physics B 2024年第3期33卷 341-349页

作者：张世平张芳军张登红丁晓彬蒋军颉录有马玉龙李麦娟 Marek Sikorski 董晨钟 Key Laboratory of atomic and molecular physics & Functional Materials of Gansu Province College of Physics and Electronic EngineeringNorthwest Normal UniversityLanzhou 730070China

The electron-impact single ionization cross section for W8+ion has been calculated using flexible atomic code,employing the level-to-level distorted-wave *** calculations takes into account contributions form both direct ionization(DI)and excitation autoionization(EA).However,the theoretical predictions,based solely on the ground state,tends to underestimate the experimental *** discrepancy can be mitigated by incorporation contributions from excited *** extended the theoretical analysis,including the contributions from the long-lived metastable states with lifetimes exceeding 1.5×10-5 *** employed two statistical models to predict the fraction of ground state ions in the parent ion *** a 79%fraction of parent ions in ground configuration,the experiment measurements align with the *** we derived the theoretical cross-section for the ground state as correlated plasma rate coefficients,and compared it with existing *** the uncertainty in our calculations,our results are still acceptable.

关键词： tungsten ions electron-impact ionization cross section

Pressure-Driven Energy Band Gap Narrowing of λ-N_(2)

在线全文

学校读者我要写书评

暂无评论

Chinese physics Letters 2024年第4期41卷 173-177页

作者：李月刘静仪吴彬彬陶雨耿延雷王晓丽雷力 Institute of atomic and molecular physics Sichuan UniversityChengdu 610065China School of physics and Electronic Information Yantai UniversityYantai 264005China

Probing the energy band gap of solid nitrogen at high pressures is of importance for understanding pressuredriven changes in electronic structures and insulator-to-metal transitions under high *** λ-N_(2) formed by cold compression is known to be the most stable one in all solid nitrogen phases observed so *** optimizing the optical system,we successfully measured the high-pressure absorption spectra of λ-N_(2) covering the polymericnitrogen synthetic pressures(124 GPa-165 GPa).The measured optical band gap decreases with increasing pressure,from 2.23 eV at 124 GPa to 1.55 eV at 165 GPa,with a negative pressure coefficient of-18.4 meV/GPa,which is consistent with the result from our ab initio total-energy calculations(-22.6 meV/GPa).The extrapolative metallization pressure for theλ-N_(2) is around 288(18)GPa,which is close to the metallization pressure(280 GPa)for the η-N_(2) expected by previous absorption edge and direct electrical *** results provide a direct spectroscopic evidence for the pressure-driven band gap narrowing of solid nitrogen.

关键词： absorption transitions spectroscopic

Tunable spectral continuous shift of high-order harmonic generation in atoms by a plasmon-assisted shaping pulse

在线全文

学校读者我要写书评

暂无评论

Chinese physics B 2024年第3期33卷 433-440页

作者：王源李玉龙乔月高娜郭福明陈洲赫兰海杨玉军赵曦王俊 Institute of atomic and molecular physics Jilin UniversityChangchun 130012China Jilin Provincial Key Laboratory of Applied atomic and molecular Spectroscopy Jilin UniversityChangchun 130012China Beijing Institute of Space Launch Technology Beijing 100076China School of physics and Information Technology Shaanxi Normal UniversityXi'an 710062China

We delve into the phenomenon of high-order harmonic generation within a helium atom under the influence of a plasmon-assisted shaping *** findings reveal an intriguing manipulation of the frequency peak position in the harmonic emission by adjusting the absolute phase parameter within the frequency domain of the shaping *** phenomenon holds potential significance for experimental setups necessitating precisely tuned single ***,we observe a modulated shift in the created harmonic photon energy,spanning an impressive range of 1.2 *** frequency peak shift is rooted in the asymmetry exhibited by the rising and falling edges of the laser pulse,directly influencing the position of the peak frequency *** study quantifies the dependence of this tuning range and the asymmetry of the laser pulse,offering valuable insights into the underlying mechanisms driving this ***,our investigation uncovers the emergence of semi-integer order harmonics as the phase parameter is *** attribute this discovery to the intricate interference between harmonics generated by the primary and secondary return *** observation introduces an innovative approach for generating semi-integer order harmonics,thus expanding our understanding of high-order harmonic ***,our work contributes to the broader comprehension of complex phenomena in laser-matter interactions and provides a foundation for harnessing these effects in various applications,particularly those involving precise spectral control and the generation of unique harmonic patterns.

关键词： high-order harmonic semi-integer-order spectra shift inhomogeneous field

Deciphering TADF Mechanisms in Metal-Free Organic Emitters BrA-HBI:Utilizing Optimally Tuned Range-Separated Functionals for Insight

在线全文

学校读者我要写书评

暂无评论

Chinese physics Letters 2024年第9期 31-36页

作者：于春悦尹航郭婕张闻天石英 Institute of atomic and molecular physics Jilin University

Metal-free organic emitters, characterized by their thermally activated delayed fluorescence(TADF) properties, offer considerable promise for the creation of highly efficient organic light-emitting diodes(OLEDs). Recently,Shao et al. presented a novel excited state intramolecular proton transfer(ESIPT) system Br A-HBI, demonstrating an emission quantum yield of up to 50% [Adv. Funct. Mater. 32, 2201256(2022)].

关键词：