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Dielectric-ion-conductive ZnNb2O6 layer enabling rapid desolvation and diffusion for dendrite-free Zn metal batteries

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Journal of Energy Chemistry 2025年第1期100卷 693-701页

作者： Haifeng Yang Jian Wang Panpan Zhang Xiaomin Cheng Qinghua Guan Jing Dong Bixian Chen Lujie Jia Jing Zhang Yongzheng Zhang Yunjian Liu Hongzhen Lin School of Materials science and engineering Jiangsu University i-Lab & CAS Key Laboratory of nanophotonic Materials and Devices Suzhou Institute of Nano-Tech and Nano-Bionics Chinese Academy of Sciences Helmholtz institute Ulm (HIU) Karlsruhe institute of Technology (KIT) School of Materials science and engineering Xi'an University of Technology State Key Laboratory of Chemical engineering East China University of Science and Technology

Rechargeable aqueous zinc-metal batteries （AZMBs） are promising candidates for large-scale energy storage systems due to their low cost and high ***,their performance and sustainability are significantly hindered by the sluggish desolvation kinetics at the electrode/electrolyte interface and the corresponding hydrogen evolution reaction where active water molecules tightly participate in the Zn（H2O）62+solvation ***,learnt from self-generated solid electrolyte interphase （SEI） in anodes,the dielectric but ion-conductive zinc niobate nanoparticles artificial layer is constructed on metallic Zn surface （ZNB@Zn）,acting as a rapid desolvation *** zincophilic and dielectric-conductive properties of ZNB layer accelerate interfacial desolvation/diffusion and suppress surface corrosion or dendrite formation,achieving uniform Zn plating/stripping behavior,as confirmed by electronic/optical microscopies and interface spectroscopical measurements together with theoretical ***,the as-prepared ZNB@Zn electrode exhibits excellent cycling stability of over 2000 h and robust reversibility （99.54%） even under high current density and depth of discharge ***,the assembled ZNB@Zn-based full cell displays high capacity-retention rate of 80.21%after 3000 cycles at 5 A g-1and outstanding rate performance up to 10 A *** large-areal pouch cell is stabilized for hundreds of cycles,highlighting the bright prospects of the dielectric but ion-conductive layer in further application of AZMBs.

关键词： Zn metal battery Dielectric artificial layer Rapid ion diffusion Zincophilic diffusion Active water inhibition

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Three dimensional K-Tz stress fields around the embedded center elliptical crack front in elastic plates

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Acta Mechanica Sinica 2006年第2期22卷 148-155页

作者： Junhua Zhao Wanlin Guo Chongmin She Bo Meng eng institute of nano science Nanjing University of Aeronautics Astronautics Nanjing 210016 China

Through detailed three-dimensional （3D） finite element （FE） calculations, the out-of-plane constraints Tz along embedded center-elliptical cracks in mode I elastic plates are studied. The distributions of Tz are obtained near the crack front with aspect ratios （a/c） of 0.2, 0.4, 0.5, 0.6, 0.8 and 1.0. Tz decreases from an approximate value of Poisson ratio v at the crack tip to zero with increasing normalized radial distances （r/a） in the normal plane of the crack front line, and increases gradually when the elliptical parameter angle φ changes from 0° to 90°at the same r/a. With a/c rising to 1.0, Tz is getting nearly independent of φ and is only related to r/a. Based on the present FE calculations for Tz, empirical formulas for Tz are obtained to describe the 3D distribution of Tz for embedded center-elliptical cracks using the least squares method in the range of 0.2 ≤ a/c ≤ 1.0. These Tz results together with the corresponding stress intensity factor K are well suitable for the analysis of the 3D embedded centerelliptical crack from field, and a two-parameter K-Tz principle is proposed.

关键词： Three-dimensional finite element Out-of-plane constraint Tz Embedded elliptical crack Stress intensity factor T-Stress Stress field

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Magnetron sputtered nickel oxide with suppressed interfacial defect states for efficient inverted perovskite solar cells

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Journal of Energy Chemistry 2025年第1期100卷 348-355页

作者： Guoqiang Ma Qin Tan Zhaoning Li Jingwei Xiu Jiafeng Wang Tianle Cheng Dong He Qiang Sun Xuhang Ma Francesco Lamberti Zhubing He Department of Materials science and engineering Institute of Innovative Materials (I2M) Shenzhen Key Laboratory of Full Spectral Solar Electricity Generation (FSSEG)Southern University of Science and Technology (SUSTech) Core Research Facilities Southern University of Science and Technology Department of Chemical sciences Department of Industrial Engineering University of Padova

Widely used spin-coated nickle oxide （NiOx） based perovskite solar cells often suffer from severe interfacial reactions between the NiOxand adjacent perovskite layers due to surface defect states,which inherently impair device performance in a long-term view,even with surface molecule *** this study,we developed high-quality magnetron-sputtered NiOxthin films through detailed process optimization,and compared systematically sputtered and spin-coated NiOxthin film surfaces from materials to *** sputtered NiOxfilms exhibit improved crystallinity,smoother surfaces,and significantly reduced Ni3+or Ni vacancies compared to their spin-coated ***,the interface between the perovskite and sputtered NiOxfilm shows a substantially reduced density of defect *** solar cells （PSCs） fabricated with our optimally sputtered NiOxfilms achieved a high power conversion efficiency （PCE） of up to 19.93%and demonstrated enhanced stability,maintaining 86.2% efficiency during 500 h of maximum power point tracking under one standard sun ***,with the surface modification using (4-(2,7-dibromo-9,9-dimethylacridin-10（9H）-yl)butyl)p hosphonic acid （DMAcPA）,the device PCE was further promoted to 23.07%,which is the highest value reported for sputtered NiOxbased PSCs so far.

关键词： Nickle oxide Magnetron sputter Defect Stability Perovskite solar cell

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A controllable hydrothermal method to prepare La(OH)_3 nanorods using new precursors

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Journal of Rare Earths 2015年第4期33卷 425-431页

作者： Mehdi Mousavi-Kamazani Sakineh Alizadeh Fateme Ansari Masoud Salavati-Niasari institute of nano science and nano Technology University of Kashan

Using the hydrothermal method, lanthanum hydroxide nanorods were synthesized by the reaction of LaC13·7H20, ethyl- enediamine, and hydrazine. According to SEM results, ethylenediamine and hydrazine with pH management could control the parti- cle growth and played an important role in formation of lanthanum hydroxide nanorods. The morphology and microstructure of the obtained products were characterized by X-ray diffraction （XRD） spectra, energy-dispersive X-ray spectroscopy （EDX）, Fourier transformed infi＇ared （FTIR） spectrum, transmission electron microscopy （TEM）, and scanning electron microscopy （SEM）. Further- more, the effects of the molar ratio of the precursors as well as the reaction temperature and time on the morphology and particle size of the products were investigated.

关键词： nanorods hydrothermal lanthanum hydroxide one-dimensional rare earths

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Zinc-based fiber-shaped rechargeable batteries:Insights into structures,electrodes,and electrolytes

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nano Research 2025年第1期18卷 278-293页

作者： Xuan Zhang Hongcheng Zhang Mengxiang Chen Jingqi Lu Evgeny Zhuravlev Jing Jiang Pin Liu Shengyang Dong Du Yuan Guoyin Zhu Lianbo Ma Yizhou Zhang institute of Advanced Materials and Flexible Electronics(IAMFE) School of Chemistry and Materials ScienceNanjing University of Information Science and TechnologyNanjing 210044China School of Materials science and engineering Anhui University of TechnologyMaanshan 243002China College of Materials science and engineering Changsha University of Science and TechnologyChangsha 410004China

The rapid evolution of flexible wearable electronics has spurred a growing demand for energy storage devices,characterized by low-cost manufacturing processes,high safety standards,exceptional electrochemical performance and robust mechanical *** novel flexible devices,fiber-shaped batteries(FSBs)have emerged as prominent solutions exceptionally suited to future applications,owing to their unique one-dimensional(1D)architecture,remarkable flexibility,potential for miniaturization,adaptability to deformation and compatibility with the conventional textile *** the forefront research on fiber-shaped batteries,zincbased FSBs(ZFSBs)have garnered significant attentions,featured by the promising electrochemical properties of metallic *** enthusiasm is driven by the impressive capacity of Zn(820 mAh·g^(-1))and its low redox potential(Zn/Zn^(2+):-0.76 V *** hydrogen electrode).This review aims to consolidate recent achievements in the structural design,fabrication processes and electrode materials of flexible ***,we highlight three representative structural configurations:parallel type,twisted type and coaxial *** also place special emphasis on electrode modifications and electrolyte ***,we delve into the promising development opportunities and anticipate future challenges associated with ZFSBs,emphasizing their potential roles in powering the next generation of wearable electronics.

关键词： zinc-based batteries fiber-shape parallel type twisted type coaxial type

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A cellulose-based lithium-ion battery separator with regulated ionic transport and high thermal stability for extreme environments

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nano Research 2025年第1期18卷 315-322页

作者： Kun-Peng Yang Song Xie Zi-Meng Han Hao-Cheng Liu Chong-Han Yin Wen-Bin Sun Zhang-Chi Ling Huai-Bin Yang De-Han Li Qing-Fang Guan Shu-Hong Yu Department of Chemistry New Cornerstone Science LaboratoryInstitute of Biomimetic Materials&ChemistryAnhui Engineering Laboratory of Biomimetic MaterialsDivision of Nanomaterials&ChemistryHefei National Research Center for Physical Sciences at the MicroscaleUniversity of Science and Technology of ChinaHefei 230026China institute of Innovative Materials Department of Materials Science and EngineeringDepartment of ChemistrySouthern University of Science and TechnologyShenzhen 518055China

Separators play a critical role in lithium-ion ***,the restrictions of thermal stability and inferior electrical performance in commercial polyolefin separators significantly limit their applications under harsh ***,we report a cellulose-assisted self-assembly strategy to construct a cellulose-based separator massively and *** an ultrahigh ionic conductivity in electrolytes of 3.7 mS·cm^(-1) and the ability to regulate ion transport,the obtained separator is a promising alternative for high-performance lithium-ion *** addition,integrated with high thermal stability,the cellulose-based separator endows batteries with high safety at high temperatures,greatly expanding the application scenarios of energy storage devices in extreme environments.

关键词： lithium-ion batteries bio-inspired materials battery separators cellulose nanofiber ultrahigh ionic conductivity high safety

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Fabrication and characterization of Fe_3O_4@SiO_2@TiO_2@Ho nanostructures as a novel and highly efficient photocatalyst for degradation of organic pollution

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Journal of Energy Chemistry 2017年第1期26卷 17-23页

作者： Sobhan Mortazavi-Derazkola Masoud Salavati-Niasari Omid Amiri Ali Abbasi institute of nano science and nano Technology University of Kashan Department of Electrical engineering and Computer science University of Michigan

In this work we synthesize a novel and highly efficient photocatalyst for degradation of methyl orange and rhodamine B. In addition, a new method for synthesis of FeO@SiO@TiO@Ho magnetic core-shell nanoparticles with spherical morphology is proposed. The crystal structures, morphology and chemical properties of the as-synthesized nanoparticles were characterized using Fourier transform infrared spectroscopy（FT-IR）, scanning electron microscopy（SEM）, transmission electron microscopy（TEM）, energy dispersive X-ray（EDS）, X-ray diffraction（XRD）, UV–vis diffuse reflectance spectroscopy（DRS） and vibrating sample magnetometer（VSM） techniques. The photocatalytic activity of FeO@SiO@TiO@Ho was investigated by degradation of methyl orange（MO） as cationic dye and rhodamine B（Rh B） as anionic dye in aqueous solution under UV/vis irradiation. The results indicate that about 92.1% of Rh B and78.4% of MO were degraded after 120 and 150 min, respectively. These degradation results show that FeO@SiO@TiO@Ho nanoparticles are better photocatalyst than Fe3O4@Si O2@TiO 2@Ho for degradation of MO and Rh B. As well as, the catalyst shows high recovery and stability even after several separation cycles.

关键词： Catalysis Adsorption chemistry Physical adsorption Chemical adsorption

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Growth of uniformly doped black phosphorus films through versatile atomic substitution

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science China(Information sciences) 2023年第6期66卷 78-86页

作者： Cheng CHEN Yang LU Chang LI Xingang HOU Yongjie WANG Junrong ZHANG Junyong WANG Kai ZHANG School of nano-Tech and nano-Bionics University of Science and Technology of China CAS Key Laboratory of nanophotonic Materials and Devices & Key Laboratory of nanodevices and Applications i-LabSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of Sciences nano science and Technology institute University of Science and Technology of China

For the emerging excellent two-dimensional semiconductor black phosphorus(BP), doping has been proven as an effective way to tune its intrinsic properties. For the further development and expansion of BP-based research and application, the direct growth of doped BP films is highly desirable but still remains a challenge. In this work, the direct growth of uniformly doped-BP films on silicon substrates is achieved by a simple one-step vapor growth. The proposed decoupled feeding strategy significantly improves the effectiveness of doping and enables uniform dopant distribution in the grown films. The substitutional doping nature and high crystal quality of the grown doped films are confirmed by microscopy and crystal structural determination. Electrical transport measurement results reveal that Se and Te dopants perform mild electron doping effect and enable improve the electron mobility relative to pristine BP, while As dopant performs mild hole doping effect. It is believed that the direct growth of doped BP films in this work will facilitate the research development of BP in electronics and optoelectronics.

关键词： black phosphorus dope vapor growth thin film two-dimensional materials

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A novel active-passive protection strategy endows carbonyl iron with excellent intelligent anti-corrosion and microwave absorption dual functional characteristics

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nano Research 2025年第1期18卷 487-500页

作者： Wei Tian Quanyuan Feng Linbo Zhang Yinfan Liu Xian Jian Longjiang Deng institute of Microelectronics School of Information Science and TechnologySouthwest Jiaotong UniversityChengdu 611756China National engineering Researching Centre of Electromagnetic Radiation Control Materials Key Laboratory of Multi-Spectral Absorbing Materials and Structures of Ministry of EducationState Key Laboratory of Electronic Thin Films and Integrated DevicesSchool of Electronic Science and EngineeringUniversity of Electronic Science and Technology of ChinaChengdu 611731China School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 611731China The Yangtze Delta Region institute(Huzhou)&School of Electronic science and engineering University of Electronic Science and Technology of ChinaHuzhou 313001China

Carbonyl iron absorbers(CI)face significant challenges in practical applications,such as corrosion,interface bonding failure,detachment,and high maintenance ***,we have developed intelligent self-healing technology based on proactive/passive mechanisms via in situ synthesis of self-healing factors(polydopamine/benzotriazole(PDA/BTA))and physical barrier layers(SiO_(2)/1,1,1,3,3,3-hexamethyl disilazane,SiO_(2)/HMDS)to enhance corrosion resistance,while also being compatible with efficient microwave absorption *** unique multiscale structure gives full play to the utilization of the roles of each functional layer,including the intelligent self-healing features of PDA/BTA,physical shielding and spatial confinement characteristics of SiO_(2)/HMDS,and magnetic-dielectric synergistic mechanism resulted from the good impedance matching characteristics,the conduction loss,the interfacial polarization loss and natural *** asfabricated composites achieved an exceptional minimum reflection loss value of-55.4 dB at 10.7 GHz and the effective absorption band of 7.6 ***,it still exhibits obvious self-healing and corrosion resistance characteristics after 360 h corrosion treatment,ascribed to the self-healing mechanism of PDA/BTA and the blocking intervention effect of SiO_(2)/*** work is considered to pave the way for the synthesis of high-performance magnetic absorbers,especially in enhancing their intelligent self-healing ability in corrosive environments.

关键词： microwave absorption intelligent self-healing technology carbonyl iron multiscale structure magneticdielectric synergistic mechanism

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Polydopamine directed MnO@C microstructures as electrode for lithium ion battery

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science China Chemistry 2016年第1期59卷 122-127页

作者： Delu Li Yejun Zhang Lun Li Feng Hu Hongchao Yang Changhong Wang Qiangbin Wang Key Laboratory.of nano-Bio Interface Division of Nanobiomedicine and i-LabSuzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of SciencesSuzhou 215123China institute of nano science and Technology University of Science and Technology of ChinaSuzhou 215123China

In this work,a facile process was reported to fabricate amorphous carbon-coated MnO micropeanuts(MPs)with 1.8μm in length and 1.0μm in width using hydrothermal reaction followed by heat treatment in the oxygen-free *** Mn Cl_2 and KMnO_4 dissolved in the mixture of ethylene glycol and water,MnCO_3 MP precursors were obtained via the hydrothermal reaction with dopamine as *** MnCO_3 MP was annealed at 600°C in the N_2 atmosphere and was transformed into MnO MP,and simultaneously the formed polydopamine during the hydrothermal reaction was carbonized to produce amorphous carbon-coating on the MnO MP *** contrast,MnCO_3 nanoparticle(NP)precursor was formed without the addition of dopamine and MnO NP agglomerates were prepared after *** carbonization of polydopamine during thermolysis improves the electrical conductivity and thermal stability of the MnO MP and thus its electrochemical performance as electrode materials for lithium ion ***,this facile strategy for fabricating and designing carbon-coated materials would inspire more novel nanostructures and applications thereof.

关键词： micropeanut Mn O lithium ion battery

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