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CO_(2)flooding in shale oil reservoir with radial borehole fracturing for CO_(2)storage and enhanced oil recovery

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Petroleum Science 2024年第1期21卷 519-534页

作者： Jia-Cheng Dai Tian-Yu Wang Jin-Tao Weng Kang-Jian Tian Li-Ying Zhu Gen-Sheng Li State Key Laboratory of Petroleum Resources and Prospecting China University of PetroleumBeijing102249China China National Oil and gas Exploration and Development company limited Beijing100034China

This study introduces a novel method integrating CO_(2)flooding with radial borehole fracturing for enhanced oil recovery and CO_(2)underground storage,a solution to the limited vertical stimulation reservoir volume in horizontal well fracturing.A numerical model is established to investigate the production rate,reservoir pressure field,and CO_(2)saturation distribution corresponding to changing time of CO_(2)flooding with radial borehole fracturing.A sensitivity analysis on the influence of CO_(2)injection location,layer spacing,pressure difference,borehole number,and hydraulic fractures on oil production and CO_(2)storage is *** CO_(2)flooding process is divided into four *** in layer spacing will significantly improve oil production rate and gas storage ***,serious gas channeling can occur when the spacing is lower than 20 *** the pressure difference between the producer and injector,the borehole number,the hydraulic fracture height,and the fracture width can also increase the oil production rate and gas storage *** analysis shows that layer spacing and fracture height greatly influence gas storage and oil *** outcomes are expected to provide a theoretical basis for the efficient development of shale oil reservoirs in the vertical direction.

关键词： Shale oil Radial borehole fracturing Embedded discrete fracture model Enhanced oil recovery Carbon storage

Hydrogen production from hydrolysis of NaBH_(4) solution over Co-Fe-B@g-C_(3)N_(4)/NF thin film catalyst

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Rare Metals 2024年第6期43卷 2648-2659页

作者： Yan Wang Jia-Xin Ma Jian Ren Di Zhang Feng-Yan Xu Ke Zhang Zhong-Qiu Cao Qiu-Ju Sun Guo-De Li Shi-Wei Wu Hong-Hui Chen College of Chemistry and Chemical Engineering Shenyang Normal UniversityShenyang 110034China Experimental Center Shenyang Normal UniversityShenyang 110034China Hunan Shande Energy storage New Materials Research Institute limited company Changde 415000China

In this study,the double loaded Co-Fe-B@g-C_(3)N_(4)/NF(NF:Ni foam)thin film catalysts were prepared for the first time via chemical deposition method at room *** optimizing the reducing agent concentration to 0.9 mol·L^(-1),the as-obtained Co-Fe-B@g-C_(3)N_(4)/NF exhibited the twisted ribbon structure with more distinct three-dimensional hierarchy and the smaller particle size,showing the good catalytic property for the hydrolysis of NaBH_(4)*** H_(2)generation rate of Co-Fe-B@g-C_(3)N_(4)/NF and binary Co-B@g-C_(3)N_(4)/NF under visible light irradiation surpassed the value under natural *** apparent activation energy of Co-Fe-B@g-C_(3)N_(4)/NF(45.0 kJ·mol^(-1))under visible light irradiation was obviously reduced when compared with the natural condition(48.4 kJ·mol^(-1))and binary Co-B@g-C_(3)N_(4)/NF(60.6 kJ·mol^(-1))under visible light ***,the catalytic performance of the optimized Co-Fe-B@g-C_(3)N_(4)/NF thin film catalyst was superior to most of the reported non-noble metal and even noble metal ***,it illustrated that the catalytic H_(2)production performance of Co-Fe-B@g-C_(3)N_(4)/NF thin film was distinctly improved after the introduction of light and multicomponent recombination.

关键词： Sodium borohydride Co-Fe-B@g-C_(3)N_(4)/NF catalyst Chemical deposition Hydrogen production

Key aspects of underground hydrogen storage in depleted hydrocarbon reservoirs and saline aquifers:A review and understanding

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Energy Geoscience

Energy Geoscience 2024年第4期5卷 55-74页

作者： Rawaa A.Sadkhan Watheq J.Al-Mudhafar Basra University of Oil and gas BasrahIraq Basrah Oil company BasrahIraq

Underground hydrogen storage is critical for renewable energy integration and *** aquifers and depleted oil and gas reservoirs represent viable large-scale hydrogen storage solutions due to their capacity and *** paper provides a comparative analysis of the current status of hydrogen storage in various ***,it assesses the geological compatibility,capacity,and security of these storage environments with minimal leakage and *** in-depth analysis was also conducted on the economic and environmental issues that impact the hydrogen *** addition,the capacity of these structures was also clarified,and it is similar to storing carbon dioxide,except for the cushion gas that is injected with hydrogen to provide pressure when withdrawing from the store to increase *** research also discusses the pros and cons of hydrogen storage in saline aquifers and depleted oil and gas *** include numerous storage sites,compatibility with existing infrastructure,and the possibility to repurpose declining oil and gas ***,it was identified that depleted gas reservoirs are better for hydrogen gas storage than depleted oil reservoirs because hydrogen gas may interact with the *** saline aquifers rank third because of uncertainty,limited capacity,construction and injection *** properties that affect the hydrogen injection process were also discussed in terms of solid,fluid,and solid-fluid *** all structures,successful implementation requires characterizing sites,monitoring and managing risks,and designing efficient storage *** findings expand hydrogen storage technology and enable a renewable energy-based energy system.

关键词： Underground hydrogen storage Renewable energy Depleted reservoirs Saline aquifers Fundamental review

Integrated Frequency-constrained Scheduling Considering Coordination of Frequency Regulation Capabilities from Multi-source Converters

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Journal of Modern Power Systems and Clean Energy 2024年第1期12卷 261-274页

作者： Jiaming Li Ying Qiao Zongxiang Lu Wei Ma Xin Cao Rongfu Sun the Department of Electrical Engineering Tsinghua UniversityBeijing 100084China the China Suntien Green Energy limited company Shijiazhuang 050011China the State Grid Jibei Electric Power company Beijing 100054China

As the proportion of renewable energy(RE)increases,the inertia and the primary frequency regulation(FR)capability of the power system ***,ensuring frequency security in the scheduling model has become a new technical requirement in power systems with a high share of *** to a shortage of conventional synchronous generators,the frequency support of multi-source converters has become an indispensable part of the system frequency resources,especially variable-speed wind turbine generation(WTG)and battery energy storage(BES).Quantitative expression of the FR capability of multi-source converters is necessary to construct frequency-constrained scheduling ***,the frequency support performance of these converter-interfaced devices is related to their working states,operation modes,and parameters,and the complex coupling of these factors has not been fully exploited in existing *** this study,we propose an integrated frequency-constrained scheduling model considering the coordination of FR capabilities from multi-source *** FR control strategies and variable FR parameters for WTG with or without reserved power are modeled,and multi-target allocation of BES capacity between tracking dispatch instruction and emergency FR is ***,the variable FR capabilities of WTG and BES are embedded into the integrated frequency-constrained scheduling *** nonlinear constraints for frequency security are precisely linearized through an improved iteration-based *** effectiveness of the proposed model is verified in a modified IEEE 24-bus standard *** results suggest that the coordinated participation of BES and WTG in FR can effectively reduce the cost of the scheduling model while meeting frequency security constraints.

关键词： Battery energy storage(BES) wind turbine generation(WTG) frequency regulation(FR) frequency security power system scheduling

Microscopic experiment on efficient construction of underground gas storages converted from water-invaded gas reservoirs

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Petroleum Exploration and Development 2024年第1期51卷 203-212页

作者： JIANG Tongwen QI Huan WANG Zhengmao LI Yiqiang WANG Jinfang LIU Zheyu CAO Jinxin PetroChina company limited Beijing 100007China National Key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing 102249China College of Petroleum Engineering China University of Petroleum(Beijing)Beijing 102249China PetroChina Petroleum&New Energies company Beijing 100007China PetroChina Research Institute of Petroleum Exploration&Development Beijing 100083China

Based on the microfluidic technology,a microscopic visualization model was used to simulate the gas injection process in the initial construction stage and the bottom water invasion/gas injection process in the cyclical injection-production stage of the underground gas storage(UGS)rebuilt from water-invaded gas *** analysis of the gas-liquid contact stabilization mechanism,flow and occurrence,the optimal control method for lifecycle efficient operation of UGS was *** results show that in the initial construction stage of UGS,the action of gravity should be fully utilized by regulating the gas injection rate,so as to ensure the macroscopically stable migration of the gas-liquid contact,and greatly improve the gas sweeping capacity,providing a large pore space for gas storage in the subsequent cyclical injection-production *** the cyclical injection-production stage of UGS,a constant gas storage and production rate leads to a low pore space *** increasing the gas storage and production rate,that is,transitioning from small volume to large volume,can continuously break the hydraulic equilibrium of the remaining fluid in the porous media,which then expands the pore space and flow *** is conducive to the expansion of UGS capacity and efficiency for purpose of peak shaving and supply guarantee.

关键词： water-invaded gas-reservoir underground gas storage cyclical injection-production gas-water contact gas storage and production rate UGS capacity expansion control method

Cleaner production of 3.5 valent vanadium electrolyte from ammonium metavanadate by ammonia reduction-sulfuric acid dissolution method

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Tungsten 2024年第3期6卷 555-560页

作者： Cheng Wang Lan-Jie Li Hao Du College of Chemical Engineering University of Chinese Academy of Sciences Institute of Process Engineering National Engineering Research Center of Green Recycling for Strategic Metal Resources Chinese Academy of Sciences Hesteel Group company limited

The vanadium redox flow battery(VRFB) has been widely used in large-scale energy storage areas due to the advantages of long lifespan and high safety. However, the high preparation cost of vanadium electrolyte limits ... 详细信息

关键词： Ammonia

A log-based method for fine-scale evaluation of lithofacies and its applications to the Gulong shale in the Songliao Basin,Northeast China

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Energy Geoscience 2024年第3期5卷 189-202页

作者： Weilin Yan Chunyan Wang Shujun Yin Zheng Wen Jiandong Zheng Xiuli Fu Zhou Feng Zhaoqian Zhang Jianhua Zhu Exploration and Development Research Institute of Daqing Oilfield company limited PetroChinaDaqingHeilongjiang163002China Research Institute of Petroleum Exploration&Development PetroChinaBeijing100083China

The Gulong shale demonstrates high clay content and pronounced thin laminations,with limited vertical variability in log curves,complicating lithofacies *** comprehend the distribution and compositional features of lithofacies in the Gulong shale for optimal sweet spot selection and reservoir stimulation,this study introduced a lithofacies classification scheme and a log-based lithofacies evaluation ***,theΔlgR method was utilized for accurately determining the total organic carbon(TOC)content;a multi-mineral model based on element-to-mineral content conversion coefficients was developed to enhance mineral composition prediction accuracy,and the microresistivity curve variations derived from formation micro-image(FMI)log were used to compute lamination density,offering insights into sedimentary *** this method,integrating TOC content,sedimentary structures,and mineral compositions,the Qingshankou Formation is classified into four lithofacies and 12 sublithofacies,displaying 90.6%accuracy compared to core description *** classification results reveal that the northern portion of the study area exhibits more prevalent fissile felsic shales,siltstone interlayers,shell limestones,and ***,the upper section primarily exhibits organic-rich felsic shale and siltstone interlayers,the middle part is characterized by moderate organic quartz-feldspathic shale and siltstone/carbonate interlayers,and the lower section predominantly features organic-rich fissile felsic/clayey felsic *** various sublithofacies in relation to seven petrophysical parameters,oil test production,and fracturing operation conditions indicates that the organic-rich felsic shales in the upper section and the organic-rich/clayey felsic shales in the lower section possess superior physical properties and oil content,contributing to smoother fracturing operation and enhanced production,thus emerging as dominant ***

关键词： Lithofacies division Formation micro-image(FMI)log Lithoscanner logging Fine-scale log-based evaluation Gulong shale

Comparative evaluation of commercial Douchi by different molds:biogenic amines,non-volatile and volatile compounds

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Food Science and Human Wellness 2024年第1期13卷 434-443页

作者： Aijun Li Gang Yang Zhirong Wang Shenglan Liao Muying Du Jun Song Jianquan Kan College of Food Science Southwest UniversityChongqing 400715China Chinese-Hungarian Cooperative Research Centre for Food Science Chongqing 400715China Laboratory of Quality&Safety Risk Assessment for Agri-products on storage and Preservation(Chongqing) Ministry of Agriculture and Rural Affairs of the People's Republic of ChinaChongqing 400715China Chongqing Key Laboratory of Speciality Food Co-Built by Sichuan and Chongqing Chongqing 400715China Shu Xiang Douchi Food Research Institute limited company Chongqing 402160China

To provide new insights into the development and utilization of Douchi artificial starters,three common strains(Aspergillus oryzae,Mucor racemosus,and Rhizopus oligosporus)were used to study their influence on the fermentation of *** results showed that the biogenic amine contents of the three types of Douchi were all within the safe range and far lower than those of traditional fermented ***-type Douchi produced more free amino acids than the other two types of Douchi,and its umami taste was more prominent in sensory evaluation(P<0.01),while Mucor-type and Rhizopus-type Douchi produced more esters and pyrazines,making the aroma,sauce,and Douchi flavor more *** to the Pearson and PLS analyses results,sweetness was significantly negatively correlated with phenylalanine,cysteine,and acetic acid(P<0.05),bitterness was significantly negatively correlated with malic acid(P<0.05),the sour taste was significantly positively correlated with citric acid and most free amino acids(P<0.05),while astringency was significantly negatively correlated with glucose(P<0.001).Thirteen volatile compounds such as furfuryl alcohol,phenethyl alcohol,and benzaldehyde caused the flavor difference of three types of *** study provides theoretical basis for the selection of starting strains for commercial Douchi production.

关键词： Douchi Starting strains Non-volatile compounds Volatile compounds Sensory evaluation

Lightweight Intrusion Detection Using Reservoir Computing

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Computers, Materials & Continua 2024年第1期78卷 1345-1361页

作者： Jiarui Deng Wuqiang Shen Yihua Feng Guosheng Lu Guiquan Shen Lei Cui Shanxiang Lyu Joint Laboratory on Cyberspace Security China Southern Power GridGuangzhou510080China College of Cyber Security Jinan UniversityGuangzhou510632China Guangdong Power Grid company limited Guangzhou510663China School of Computer Science and Technology Guangdong University of TechnologyGuangzhou510006China China Southern Power Grid Extra High Voltage Transmission CompanyGuangzhouChina

The blockchain-empowered Internet of Vehicles(IoV)enables various services and achieves data security and privacy,significantly advancing modern vehicle ***,the increased frequency of data transmission and complex network connections among nodes also make them more susceptible to adversarial *** a result,an efficient intrusion detection system(IDS)becomes crucial for securing the IoV *** IDSs based on convolutional neural networks(CNN)often suffer from high training time and storage *** this paper,we propose a lightweight IDS solution to protect IoV against both intra-vehicle and external *** approach achieves superior performance,as demonstrated by key metrics such as accuracy and ***,our method achieves accuracy rates ranging from 99.08% to 100% on the Car-Hacking dataset,with a remarkably short training time.

关键词： Echo state network intrusion detection system Internet of Vehicles reservoir computing