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Effects of 1-methylcyclopropene on skin greasiness and quality of'Yuluxiang'pear during storage at 20℃

Journal of Integrative Agriculture 2024年第7期23卷 2476-2490页

作者： Wanting Yu Xinnan Zhang Weiwei Yan Xiaonan Sun Yang Wang Xiaohui Jia Research institute of pomology Chinese Academy of Agricultural SciencesXingcheng 125100China

During storage at 20℃,specific pear cultivars may exhibit a greasy texture and decline in quality due to fruit *** these varieties,‘Yuluxiang’is particularly susceptible to peel greasiness,resulting in significant economic ***,there is an urgent need for a preservative that can effectively inhibit the development of *** studies have demonstrated the efficacy of 1-methylcyclopropene(1-MCP)in extending the storage period of *** hypothesize that it may also influence the occurrence of postharvest peel greasiness in the‘Yuluxiang’*** this study,we treated‘Yuluxiang’pears with *** stored them at 20℃while analyzing the composition and morphology of the surface waxes,recording enzyme activities related to wax synthesis,and measuring indicators associated with fruit storage quality and physiological *** results demonstrate that prolonged storage at 20℃leads to a rapid increase in skin greasiness,consistent with the observed elevations in L^(*),greasiness score,and the content of total wax and greasy wax ***,there were indications that cuticular waxes underwent melting,resulting in the formation of an amorphous *** comparison to controls,the application of 1-MCP significantly inhibited increments in L^(*) values as well as grease scores while also reducing accumulation rates for oily waxes throughout most stages over its shelf period,additionally delaying transitions from flaky-wax structures towards their amorphous *** the initial 7 d of storage,several enzymes involved in the biosynthesis and metabolism of greasy wax components,including lipoxygenase(LOX),phospholipase D(PLD),andβ-ketoacyl-CoA synthase(KCS),exhibited an increase followed by a subsequent *** activity of LOX during early shelf life(0–7 d)and the KCS activity during middle to late shelf life(14–21 d)were significantly suppressed by ***,1-MCP effectively maintained firmness,

关键词： ‘Yuluxiang’pear skin greasiness 1-methylcyclopropene storage quality

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Abundance and sources of particulate polycyclic aromatic hydrocarbons and aromatic acids at an urban site in central China

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Journal of Environmental Sciences 2024年第8期142卷 155-168页

作者： Luqi Shang Zhe Dong Zihan Li Mingkai Wang Zihan Kong Xiao Li Ruiqin Zhang School of Ecology and Environment Zhengzhou UniversityZhengzhou 450001China College of Chemistry Zhengzhou UniversityZhengzhou 450001China institute of Environmental Sciences Zhengzhou UniversityZhengzhou 450001China

We conducted a simultaneous field study of PM_(2.5)-bound particulate polycyclic aromatic hydrocarbons(PAHs)and aromatic acids(AAs)in a polluted city zhengzhou to explore the concentration,sources and potential conversion pathways between PAHs and AAs in different *** average concentrations of PM_(2.5),28PAHs and 8AAs during the sampling period were 77μg/m^(3),75 ng/m^(3),and 283 ng/m^(3),*** concentration of both28PAHs and 8AAs were highest in winter and lowest in summer with ratios of 6.3 and 2.3,*** with 5-7 rings were the main components of PAHs(52%),followed by 4rings PAHs(30%)and 2-3 rings PAHs(18%).According to the source appointment results obtained by positive matrix factorization,the main sources of PAHs were combustion and vehicle emissions,which account for 37%and 34%,respectively.8AAs were divided into three groups,including four benzene dicarboxylic acids(B2CAs),three benzene tricarboxylic acids(B3CAs)and one benzene tetracarboxylic acid(B4CA).And interspecies correlation analysis with PM_(2.5)source markers were used to investigate potential *** acid(o-Ph)was the most abundant specie of 8AAs(157 ng/m^(3),55%of 8AAs),which was well correlated with ***,B3CAs and B4CA were highly correlated with sulfate and weakly correlated with levoglucosan,suggesting that secondary formation was their main *** logical oxidation products of PAHs,o-Ph and B3CAs showed good correlations with a number of PAHs,indicating possible photochemical oxidation pathway by *** addition,O_(3),NO_(2),temperature and relative humidity have positive effects on the secondary formation of B3CAs.

关键词： Polycyclic aromatic hydrocarbons Aromatic acids Source appointment Secondary formation

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Nano friction behaviour between magnetic materials and copper considering the inter-diffusion effect

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Friction 2024年第7期12卷 1532-1547页

作者： Zilin LI Lisha DOU Shiyu YANG Huajiang OUYANG Qichen ZHU Xiaoyang CHEN Xin JIA Shuaiwei DOU Xiaolong CUI Yudong ZHANG Jingjiang QIU Guochen QI Bangbang NIE Pan LIU Ronghan WEI School of Mechanics and Safety Engineering Zhengzhou UniversityZhengzhou 450001China Engineering Technology Research Center of Henan Province for MEMS Manufacturing and Application Zhengzhou UniversityZhengzhou 450001China institute of Intelligent Sensing Zhengzhou UniversityZhengzhou 450001China School of Engineering University of LiverpoolLiverpool L693GHUK School of Cyber Science and Engineering&Hanwei institute of Internet of Things Zhengzhou UniversityZhengzhou 450001China

Copper,permalloy,cobalt,and silicon are the materials that have been widely utilised in magnetic *** the size of interest is down to the nanoscale,the inter-diffusion between certain materials becomes *** paper studies the nanoscale friction characteristics between frictional pairs with and without inter-diffusion properties through the atomic force *** distinct evolution features of nanoscale friction force when inter-diffusion is involved are discovered experimentally,which is also confirmed through theoretical ***,through the thin film deposition method,four pairs of contact materials(Cu–Ni_(81)Fe_(19),Si–Ni_(81)Fe_(19),Cu–Co,Cu–Si)are designed for friction tests,in which diffusion occurs at the interface of Cu–Ni_(81)Fe_(19)***,the effects of sliding velocity and loading force on the nano friction of each pair are *** is found that regardless of the diffusion phenomenon:(1)the adhesion force values exhibit a notable correlation to the values of the friction force;(2)the friction force in all four material pairs consistently increases with the growth of the normal loading force,although the growth rate may *** terms of the sliding velocity effect,the friction forces of immiscible materials(Si–Ni_(81)Fe_(19),Cu–Co,and Cu–Si)are found to increase with the increasing sliding ***,the friction force of Cu–Ni_(81)Fe_(19),decreases with the increasing sliding ***,a compositive friction model considering both the velocity and the normal force effect was proposed,which shows good agreement with the experimental results and explains the nano friction behaviour of both miscible and immiscible metals.

关键词： atomic force microscope friction force normal load sliding velocity

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TET1 Participates in Complete Freund’s Adjuvant-induced Trigeminal Inflammatory Pain by Regulating Kv7.2 in a Mouse Model

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Neuroscience Bulletin 2024年第6期40卷 707-718页

作者： Dengcheng Zhan Jingjing Zhang Songxue Su Xiuhua Ren Sen Zhao Weidong Zang Jing Cao Department of Human Anatomy School of Basic Medical SciencesZhengzhou UniversityZhengzhou450001China Neuroscience Research institute Zhengzhou UniversityZhengzhou450001China

Trigeminal inflammatory pain is one of the most severe pain-related disorders in humans;however,the underlying mechanisms remain largely *** this study,we investigated the possible contribution of interaction between ten-eleven translocation methylcytosine dioxygenase 1(TET1)and the voltage-gated K^(+)channel Kv7.2(encoded by Kcnq2)to orofacial inflammatory pain in *** found that complete Freund’s adjuvant(CFA)injection reduced the expression of Kcnq2/Kv7.2 in the trigeminal ganglion(TG)and induced orofacial inflammatory *** involvement of Kv7.2 in CFA-induced orofacial pain was further confirmed by Kv7.2 knockdown or ***,TET1 knockdown in Tet1^(flox/flox)mice significantly reduced the expression of Kv7.2 and M currents in the TG and led to pain-like ***,TET1 overexpression by lentivirus rescued the CFA-induced decreases of Kcnq2 and M currents and alleviated mechanical *** data suggest that TET1 is implicated in CFA-induced trigeminal inflammatory pain by positively regulating Kv7.2 in TG neurons.

关键词： Facial pain KCNQ2 potassium channel TET1 protein

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An anonymous authentication and secure data transmission scheme for the Internet of Things based on blockchain

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Frontiers of Computer Science 2024年第3期18卷 183-197页

作者： Xingxing CHEN Qingfeng CHENG Weidong YANG Xiangyang LUO State Key Laboratory of Mathematical Engineering and Advanced Computing Zhengzhou Institute of Information Science and TechnologyZhengzhou 450001China Henan Key Laboratory of Grain Photoelectric Detection and Control Henan University of TechnologyZhengzhou 450001China Henan Province Key Laboratory of Cyberspace Situation Awareness Zhengzhou Institute of Information Science and TechnologyZhengzhou 450001China

With the widespread use of network infrastructures such as 5G and low-power wide-area networks,a large number of the Internet of Things(IoT)device nodes are connected to the network,generating massive amounts of ***,it is a great challenge to achieve anonymous authentication of IoT nodes and secure data *** present,blockchain technology is widely used in authentication and s data storage due to its decentralization and ***,Fan et *** a secure and efficient blockchain-based IoT authentication and data sharing *** studied it as one of the state-of-the-art protocols and found that this scheme does not consider the resistance to ephemeral secret compromise attacks and the anonymity of IoT *** overcome these security flaws,this paper proposes an enhanced authentication and data transmission scheme,which is verified by formal security proofs and informal security ***,Scyther is applied to prove the security of the proposed ***,it is demonstrated that the proposed scheme achieves better performance in terms of communication and computational cost compared to other related schemes.

关键词： Internet of Things blockchain authentication data transmission

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Cation-Anion Redox Active Organic Complex for High Performance Aqueous Zinc Ion Battery

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Energy & Environmental Materials 2024年第1期7卷 60-67页

作者： Lilin Zhang Yining Chen Zongyuan Jiang Jingwei Chen Cong Wei Wenzhuo Wu Shaohui Li Qun Xu School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China Henan institute of Advanced Technology Zhengzhou UniversityZhengzhou 450001China School of Materials Science and Engineering Ocean University of China Qingdao 266100China

Organic redox compounds are attractive cathode materials in aqueous zinc-ion batteries owing to their low cost,environmental friendliness,multiple-electron-transfer reactions,and resource ***,the realized energy density is constrained by the limited capacity and low ***,copper-tetracyanoquinodimethane(CuTCNQ),an organic charge-transfer complex is evaluated as a zinc-ion battery cathode owing to the good electron acceptation ability in the cyano groups that improves the voltage *** electrochemical activation,electrolyte optimization,and adoption of graphene-based separator,CuTCNQ-based aqueous zinc-ion batteries deliver much improved rate performance and cycling stability with anti-self-discharge *** structural evolution of CuTCNQ during discharge/charge are investigated by ex situ Fourier transform infra-red(FT-IR)spectra,ex situ X-ray photoelectron spectroscopy(XPS),and in situ ultraviolet visible spectroscopy(UV-vis),revealing reversible redox reactions in both cuprous cations(Cu^(+))and organic anions(TCNQ^(x-1)),thus delivering a high voltage output of 1.0 V and excellent discharge capacity of 158 mAh g^(-1).The remarkable electrochemical performance in Zn//CuTCNQ is ascribed to the strong inductive effect of cyano groups in CuTCNQ that elevated the voltage output and the graphene-modified separator that inhibited CuTCNQ dissolution and shuttle effect in aqueous electrolytes.

关键词： cathode materials cyano groups electrochemical activation organic charge-transfer complex zinc-ion battery

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Acute suppurative terminal cholangitis:Clinical characteristics of a new subtype of acute cholangitis

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Hepatobiliary & Pancreatic Diseases International 2024年第3期23卷 293-299页

作者： Rong-Tao Zhu Ye Li Chi-Xian Zhang Wei-Jie Wang Ruo-Peng Liang Jian Li Kai Bai Yu-Ling Sun Department of Hepatobiliary and Pancreatic Surgery the First Affiliated Hospital of Zhengzhou UniversityZhengzhou 450052China zhengzhou Key Laboratory of Hepatobiliary and Pancreatic Diseases Zhengzhou 450052China institute of Hepatobiliary and Pancreatic Diseases Zhengzhou UniversityZhengzhou 450052China Department of Pathology the First Affiliated Hospital of Zhengzhou UniversityZhengzhou 450052China

Background:Acute suppurative terminal cholangitis(ASTC)is rarer than acute obstructive cholangitis and is not well *** explore this subtype of acute cholangitis,we described our clinical experience with ***:We performed a retrospective review of patients with ASTC admitted to our center from September 2014 to August *** analyzed their clinical characteristics,including etiology,clinical manifestations,imaging features,treatment and ***:A total of 32 ASTC patients were included in the *** majority of the patients had a history of biliary operations,and clinical manifestations were occult and *** positive rate of bacterial culture was 46.9%.All the patients had typical imaging features on computed tomography and magnetic resonance *** with effective antibiotics was provided as soon as diagnosis was *** treatment,most patients had a good *** levels of total bilirubin,aspartate aminotransferase,procalcitonin and gamma-glutamyltransferase were the characteristics of critically ill patients and were associated with relatively poor ***:Our results demonstrated that ASTC should be recognized as a new subtype of acute cholangitis,and that earlier diagnosis and more personalized treatments are needed.

关键词： Acute suppurative terminal cholangitis Acute cholangitis Gram-negative bacterial infections Diagnosis Treatment

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CO2-Induced Modulation of Si-O Bonds for Low Temperature Plastic Deformation of Amorphous Silica Nanoparticles with Enhanced Photoluminescence

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Energy & Environmental Materials 2024年第4期7卷 404-412页

作者： Kang Huang Wenzhuo Wu Song Xu Pengfei Yan Zhongming Wei Qun Xu Henan institute of Advanced Technology Zhengzhou University College of Materials Science and Engineering Zhengzhou University State Key Laboratory of Superlattices and Microstructures institute of Semiconductors Chinese Academy of Sciences

Modulation of Si-O bonds under mild conditions has been a challenging issue in the field of material science,which is critical to manufacture highperformance silica-based optical and photonic ***,we introduce a nondestructive technique to achieve Si-O bond rearrangement,leading to plastic deformation and photoluminescence enhancement of amorphous silica nanoparticles using supercritical carbon dioxides in EtOH/H2O solution under mild temperature.

关键词： amorphous silica anisotropic stress photoluminescence plastic deformation supercritical CO2

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Mechanism of slag pellets sticking on the wall of reduction pot in magnesium production by Pidgeon process

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Journal of Magnesium and Alloys 2024年第6期12卷 2397-2412页

作者： Jilei Xu Jinhui Liu Dong Guo Mao Chen Peixu Yang Rongbin Li Shaojun Zhang School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China Henan Province Industrial Technology Research institute of Resources and Materials Zhengzhou UniversityZhengzhou 450001China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China

In the preparation of magnesium by Pidgeon process,the phenomenon slag pellets sticking on the wall of reduction pot always appear,and the glaze sticking on the inner wall of the reduction pot is difficult to *** mechanism of this phenomenon is studied in this work by X-ray fluorescence spectrometer(XRF)measurement,electron probe microanalyzer scanning(EPMA)analysis,differential scanning calorimetry(DSC)analysis,and thermodynamic *** main components of the glaze are MgO,Ca_(12)Al_(14)F_(2)O_(32),CaF_(2),CaO,and a small amount of Ca_(4)Si_(2)O_(7)F_(2).The solid-liquid transition temperature of Ca_(12)Al_(14)F_(2)O_(32)and CaF_(2)is close to the production temperature of Pidgeon process,which leads to the bonding between the slag pellets and the pot *** loss of CaF_(2)in glaze layer will reduce the total amount of liquid phase and increase the temperature at which Ca_(12)Al_(14)F_(2)O_(32)is completely transformed into liquid phase,which causes glaze layer sticking on the inner wall of the reduction pot.

关键词： Pidgeon process Glaze Ca_(12)Al_(14)F_(2)O_(32) CaF_(2) Solid-liquid transition

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Triggering triplet excitons of carbon nanodots through nanospace domain confinement for multicolor phosphorescence in aqueous solution

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Nano Research 2024年第7期17卷 6534-6543页

作者： Ya-Chuan Liang Qing Cao Yuan Deng Yong Wang Kai-Kai Liu Chong-Xin Shan School of Electronics and Information Zhengzhou University of Light IndustryZhengzhou 450002China Henan Key Laboratory of Diamond Optoelectronic Material and Devices Key Laboratory of Material PhysicsMinistry of EducationSchool of Physics and MicroelectronicsZhengzhou UniversityZhengzhou 450001China Academy for Quantum Science and Technology Zhengzhou University of Light IndustryZhengzhou 450002China institute of Quantum Materials and Physics Henan Academy of SciencesZhengzhou 450046China

Easy non-radiative decay property of long-lived triplet excitons in aqueous solution obstructs their applications in aquatic *** reported phosphorescence phenomena in aqueous solution have excited researchers enormously but achieving full-color water-soluble phosphorescent carbon nanodots(CNDs)is still a challenging ***,full-color phosphorescence of water-soluble CNDs has been demonstrated by triggering their triplet excitons through nanospace domain confinement,and Förster energy resonance transfer is used for further tuning phosphorescence *** phosphorescence spans across most of the visible spectrum,ranging from 400 to 700 *** an aqueous solution,the CNDs exhibits blue,green,and red phosphorescence,lasting for approximately 6,10,and 7 s,***,the phosphorescence quantum yields are 11.85%,8.6%and 3.56%,making them readily discernible to the naked eyes and laying a solid foundation for practical ***,phosphorescence flexible optical display and bioimaging have been demonstrated by using the multicolor CNDs-based nanomaterials,showing distinct superiority for accuracy and complete display and imaging in complex emission background.

关键词： carbon nanodots triplet excitons multicolor aqueous solution

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