检索结果-南通市图书馆

Experimental and theoretical investigation of sulfur-doped g-C_(3)N_(4)nanosheets/FeCo_(2)O_(4)nanorods S-scheme heterojunction for photocatalytic H_(2)evolution

引用

Nano Research 2024年第9期17卷 8007-8016页

作者： Haitao Wang Lianglang Yu Jiahe Peng Jing Zou Weiping Gong Jizhou Jiang School of Chemistry and Environmental engineering School of Environmental Ecology and Biological EngineeringKey Laboratory of Green Chemical Engineering Process of Ministry of EducationEngineering Research Center of Phosphorus Resources Development and Utilization of Ministry of EducationNovel Catalytic Materials of Hubei Engineering Research CenterWuhan Institute of TechnologyWuhan 430205China Guangdong Provincial Key Laboratory for Electronic Functional Materials and Devices Huizhou UniversityHuizhou 516007China

g-C_(3)N_(4)emerges as a promising metal-free semiconductor photocatalyst due to its cost-effectiveness,facile synthesis,suitable visible light response,and robust thermal ***,its practical application in photocatalytic hydrogen evolution reaction(HER)is impeded by rapid carrier recombination and limited light absorption *** this study,we successfully develop a novel g-C_(3)N_(4)-based step-scheme(S-scheme)heterojunction comprising two-dimensional(2D)sulfur-doped g-C_(3)N_(4)nanosheets(SCN)and one-dimensional(1D)FeCo_(2)O_(4)nanorods(FeCo_(2)O_(4)),demonstrating enhanced photocatalytic HER *** engineered SCN/FeCo_(2)O_(4)S-scheme heterojunction features a well-defined 2D/1D heterogeneous interface facilitating directed interfacial electron transfer from FeCo_(2)O_(4)to SCN,driven by the lower Fermi level of SCN compared to FeCo_(2)O_(4).This establishment of electron-interacting 2D/1D S-scheme heterojunction not only facilitates the separation and migration of photogenerated carriers,but also enhances visible-light absorption and mitigates electron-hole pair *** structure analysis and density functional theory calculations corroborate that the carrier migration in the SCN/FeCo_(2)O_(4)photocatalyst adheres to a typical S-scheme heterojunction mechanism,effectively retaining highly reactive photogenerated ***,the optimized SCN/FeCo_(2)O_(4)heterojunction exhibits a substantially high hydrogen production rate of 6303.5μmol·g^(-1)·h^(-1)under visible light excitation,which is 2.4 times higher than that of the ***,the conjecture of the S-scheme mechanism is confirmed by in situ XPS *** 2D/1D S-scheme heterojunction established in this study provides valuable insights into the development of high-efficiency carbon-based catalysts for diverse energy conversion and storage applications.

关键词： g-C_(3)N_(4) FeCo_(2)O_(4) S-scheme heterojunction photocatalytic hydrogen evolution reaction(HER)

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Early Triassic Legoupil Formation in Schmidt Peninsula,Antarctic Peninsula:Provenance and Depositional Settings

引用

Journal of Earth Science 2024年第2期35卷 317-331页

作者： Chao Zhang Ying-Chun Cui Chen-Guang Liu Fang-Hua Cui Lu-Yuan Wang Wei-Qiang Zhang School of resources and Environmental engineering Shandong University of TechnologyZibo255049China MNR Key Laboratory for Polar Science Polar Research Institute of ChinaShanghai201209China Key Laboratory of Marine Sedimentology and Environmental Geology First Institute of OceanographyState Oceanic AdministrationQingdao266061China Laboratory for Marine Geology Qingdao National Laboratory for Marine Science and TechnologyQingdao266061China Key Laboratory of Mineral resources Evaluation in Northeast Asia Ministry of Land and ResourcesChangchun130061China

Geochemical compositions can be used to determine the tectonic setting of sedimentary basins,while where the link of source to sink is no longer preserved,detrital zircon age patterns can aid in resolving the original basin *** metasedimentary Legoupil Formation,located at Cape Legoupil and the Schmidt Peninsula,could give a hint for the tectonic evolution of Antarctic *** this contribution,we constrain the sedimentary provenance of the Legoupil Formation through geochemistry and detrital zircon U-Pb *** petrography and geochemical features indicate that the provenance of the Legoupil Formation could be felsic *** zircon grains record a steady supply of Permian and Ordovician material into the Legoupil *** youngest concordant zircon ages of 262 Ma suggest that the depositional time of Legoupil Formation is no older than Late *** detrital zircon age spectrum of Legoupil Formation suggests that the Legoupil Formation sediments should be derived from regional sources endemic to western Gondwana prior to its *** with the previous studies,geochemistry and detrital zircons reflect an active continental margin tectonic setting and the detrital zircon spectra of Legoupil Formation are similar to the ones deposited in forearc tectonic setting.

关键词： Schmidt Peninsula Legoupil Formation Trinity Peninsula Group detrital zircons Antarctic Peninsula geochemistry

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Hydrogen-based mineral phase transformation mechanism investigation of pyrolusite ore

引用

International Journal of Minerals,Metallurgy and Materials 2024年第11期31卷 2445-2457页

作者： Ruofeng Wang Shuai Yuan Yanjun Li Peng Gao Ru Li School of resources and Civil engineering Northeastern UniversityShenyang 110819China National-local Joint engineering Research Center of High-efficient exploitation technology for Refractory Iron Ore resources Shenyang 110819China

Pyrolusite comprises the foremost manganese oxides and is a major source of manganese *** innovative hydrogenbased mineral phase transformation technology to pyrolusite was proposed,where a 96.44%distribution rate of divalent manganese(Mn^(2+))was observed at an optimal roasting temperature of 650℃,a roasting time of 25 min,and an H2 concentration of 20vol%;under these *** manganese predominantly existed in the form of *** study investigated the generation mechanism of manganosite based on the reduction kinetics,phase transformation,and structural evolution of pyrolusite and revealed that high temperature improved the distribution rate,and the optimal kinetic model for the reaction was the random nucleation and growth model(reaction order,n=3/2)with an activation energy(E_(a))of 24.119 kJ·mol^(−1).Throughout the mineral phase transformation,manganese oxide from the outer layer of particles moves inward to the *** addition,pyrolusite follows the reduction sequence of MnO_(2)→Mn_(2)O_(3)→Mn_(3)O_(4)→MnO,and the reduction of manganese oxides in each valence state simultaneously *** findings provide significant insight into the efficient and clean utilization of pyrolusite.

关键词： reduction pyrolusite phase transformation microstructural evolution

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Layer-by-layer fabrication of montmorillonite coating immobilizing Cu_(2)O nanoparticles for continuously catalyzing glycerol to dihydroxyacetone

引用

Chinese Journal of Chemical engineering 2024年第4期68卷 263-275页

作者： Kejin Li Jiahui Liu Dajian Li Xiaolan Chen Chunhui Zhou Research Group for Advanced Materials&Sustainable Catalysis(AMSC) State Key Laboratory Breeding Base of Green Chemistry-Synthesis TechnologyCollege of Chemical EngineeringZhejiang University of TechnologyHangzhou 310032China Qing Yang institute for Industrial Minerals Qingyang 242804China engineering Research Center of Non-metallic Minerals of Zhejiang Province Zhejiang Institute of Geology and Mineral ResourcesHangzhou 310007China

Microreactors are increasingly used for green and safe chemical processes owing to their benefits of superior mass and heat transfer,increased yield,safety,and simplicity of ***,immobilizing catalysts in microreactors remains *** this investigation,a technique for creating Cu_(2)O/montmorillonite catalyst coating,using electrostatic attraction for layer-by-layer self-assembly,was *** montmorillonite film's morphology and thickness could be efficiently regulated by adjusting the degree of exfoliation and surface charge of montmorillonite,alongside layer-by-layer coating *** Cu_(2)O nanoparticles were immobilized using the flow deposition *** resulting Cu_(2)O@montmorillonite-film-coated capillary microreactor successfully transformed glycerol into *** conversion of glycerol and product selectivity could be controlled by adjusting the molar ratio of reactants,temperature,residence time,and Cu_(2)O *** maximum glycerol conversion observed was 47.6%,with a 27%selectivity toward *** study presents a technique for immobilizing montmorillonite-based catalyst coatings in capillary tubing,which can serve as a foundation for the future application of microreactors in glycerol conversion.

关键词： Microreactor Coating Montmorillonite Glycerol Cu_(2)O

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

An Application of Finite Volume WENO Schemeto Numerical Modeling of Tidal Current

引用

China Ocean engineering 2006年第4期20卷 545-556页

作者：杨中华槐文信曾小辉 State Key Laboratory of water resources and hydropower engineering Science Wuhan University The Second investigation and Design institute of China Transportation engineering

A depth-averaged 2-D numerical model for unsteady tidal flow in estuaries is established by use of the finite volume WENO scheme which maintains both uniform high order accuracy and an essentially non-oscillatory shock transition on unstructured triangular grid. The third order TVD Range-Kutta method is used for time discretization. The model has been firstly tested against four cases： 1） tidal forcing, 2） seiche oscillation, 3） wind setup in a closed bay, and 4） onedimensional dam-break water flow. The results obtained in the present study compare well with those obtained from the corresponding analytic solutions idealized for the above four cases. The model is then applied to the simulation of tidal circulation in the Yangpu Bay, and detailed model calibration and verification have been conducted with measured tidal current in the spring tide, middle tide, and neap tide. The overall performance of the model is in qualitative agreement with the data observed in 2005, and it can be used to calculate the flow in estuaries and coastal waters.

关键词： tidal current numerical modeling WENO scheme unstructured triangular grid

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Quantitative Study on Morphological Change Characteristics of Tonle Sap Lake Based on DEM

引用

Open Journal of Modern Hydrology 2024年第1期14卷 1-13页

作者： Yan Huang Yifei Tian Changwen Li Wu Liu Nan Zhang Haiyang Wang Yue Wu Wanting Feng Yifan Yu College of Civil engineering and Architecture China Three Gorges University Yichang China Bureau of Hydrology Changjiang Water Resources Commission Wuhan China College of Hydraulic and Environmental engineering China Three Gorges University Yichang China POWERCHINA hydropower Development Group Co. Ltd. Chengdu China

Lake is an important part of the natural ecosystem, and its morphological characteristics reflect the capacity of lake regulation and storage, the strength of material migration, and the characteristics of shoreline development. In most existing studies, remote sensing images are used to quantify the morphological characteristics of lakes. However, the extraction accuracy of lake water is greatly affected by cloud cover and vegetation cover, and the inversion accuracy of lake elevation data is poor, which cannot accurately describe the response relationship of lake landscape morphology with water level change. Therefore, this paper takes Tonle Sap Lake as the research object, which is the largest natural freshwater lake in Southeast Asia. DEM is constructed based on high-resolution measured topographic data, and morphological indicators such as lake area, lake shoreline length, perimeter area ratio, longest axis length, maximum width, shoreline development index, lake shape complexity, compactness ratio and form ratio are adopted to researching the evolution law of high water overflows and low water outbursts quantitatively, and clarifying the variation characteristics of landscape morphology with water level gradient in Tonle Sap Lake. The research results have important theoretical significance for the scientific utilization of Tonle Sap Lake water resources and the protection of the lake ecosystem.

关键词： Tonle Sap Lake DEM Geometrical Morphology Variation Characteristic

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Catalytic activation of peroxodisulfate using shape-controlled cerium-manganese composite oxide for phenol degradation:Kinetics and degradation pathway investigation

引用

Journal of Rare Earths 2024年第8期42卷 1514-1523,I0004页

作者： Yanxia Zheng Lixi Yang Chuxin Huang Yuchao Li Cuncun Zuo Tingting Ge Haofei Huang Jiutao An Ming Wang Yansong Zhao institute of Clean Chemical Technology School of Chemistry and Chemical EngineeringShandong University of TechnologyZibo255000China Shandong Collegial engineering Research Center of Novel Rare Earth Catalysis Materials Shandong University of TechnologyZibo255000 China College of resources and Environment engineering Shandong University of TechnologyZibo255000China Department of Safety Chemistry and Biomedical Laboratory SciencesFaculty of Engineering and ScienceWestern Norway University of Applied Sciences(HVL)5063BergenNorway

Phenol-containing wastewater is typical organic wastewater,and its treatment is *** advanced method to treat this type of wastewater is persulfate *** friendly ceriummanganese composite oxide materials were synthesized by hydrothermal method and applied to the phenol degradation *** ratios of cerium and manganese,as well as the amount of sodium hydroxide,were *** solid solutions of cerium and manganese were formed and confirmed by X-ray diffraction(XRD) and transmission electron microscopy(TEM).H_(2)-temperature programmed reduction(H_(2)-TPR) and X-ray photoelectron spectroscopy(XPS) were utilized to analyze the synergistic effect of cerium and *** is found that there is a transformation between Ce^(4+)/Ce^(3+) and Mn^(2+)/Mn^(3+),which makes the material more trivalent manganese and thereby increases the catalytic *** effect of materials in catalyzing phenol degradation by peroxodisulfate(PDS) under various preparation conditions is discussed and high-effciency removal of phenol can be achieved and the removal rate at 180 min is close to 100%.The kinetic of this process was investigated and activation energy of phenol degradation is 62,35 kJ/*** degradation pathway of phenol was studied and it is found that PDS can be activated by low metal ions and the OH and SO_(4·)^(-)radicals play crucial roles according to the quenching experiments.

关键词： Advanced oxidation process Persulfate Mn-Ce solid solution Phenol degradation Rare earths

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Evaluation of the Shallow Gas Hydrate Production Based on the Radial Drilling-Heat Injection-Back Fill Method

引用

Journal of Ocean University of China 2024年第1期23卷 119-128页

作者： CHEN Qiang WAN Yizhao WU Nengyou SUN Jianye WANG Jian LIU Changling LI Yanlong LI Chengfeng HU Gaowei Key Laboratory of Gas Hydrate Ministry of Natural ResourcesQingdao 266071China Laboratory for Marine Mineral resources Laoshan LaboratoryQingdao 266071China CNPC Offshore engineering Company Limited Beijing 100028China Technology Innovation Center for Marine Methane Monitoring Ministry of Natural ResourcesQingdao 266071China

It has been evidenced that shallow gas hydrate resources are abundant in deep oceans *** geological back-ground,occurrence,and other characteristics differ significantly from deep-seated *** of the high risk of well construction and low production efficiency,they are difficult to be recovered by using conventional oil production *** a result,this paper proposes an alternative design based on a combination of radial drilling,heat injection,and backfilling ***-branch holes are used to penetrate shallow gas hydrate reservoirs to expand the depressurization area,and heat injection is utilized as a supplement to improve gas *** information collected from an investigation site close to the offshore production well in the South China Sea is used to assess the essential components of this plan,including well construction stability and gas production *** demonstrates that the hydraulic fracturing of the 60mbsf overburden layer can be prevented by regulating the drilling fluid ***,the traditional well structure is unstable,and the suction anchor is advised for better mechanical *** gas produc-tion rate can be significantly increased by combining hot water injection and depressurization ***,the suitable produc-tion equipment already in use is discussed.

关键词： shallow gas hydrate trail production radial drilling-heat injection-back fill method experimental and numerical simulation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Study of risk acceptance criteria for dams

引用

Science China(Technological Sciences) 2015年第7期58卷 1263-1271页

作者： LI ShouYi ZHOU XingBo WANG YuJie ZHOU JianPing DU XiaoHu CHEN ZuYu institute of water resources and hydropower engineering Xi'an University of Technology Department of Geotechnical engineering China Institute of Water Resources and Hydropower Research Power Construction Corporation of China Ltd. China Renewable Energy engineering institute

This paper discusses the methods of establishing risk criteria for dams and reviews the application of dam risk criteria for individuals and societies in different countries or districts. Given the conditions in China and considering the public safety and acceptance of dam risk, historical dam break data and current design standards, individual and societal risk criteria for dams are proposed. The tolerable dam risk criteria for individuals should be set to 10-5-10-7 per annum based on project scale, for ex- ample, approximately 1.0xl0 7 per annum, which corresponds to a reliability index of 4.2 based on a 100-year lifespan for a first-class or large project. The societal limit for risk tolerance for dams should be set to approximately 10-3-10-5 per annum, corresponding to the fatality range from 1 to 100 and be horizontally extended to 1000, and F-N curves are proposed. It was also found that the reliability indices of Chinese Standard （GB 50199-2013） and Eurocodel （2002） are different, but they have the same level of safety measured by the annual probability of failure. The research results have significance for establishing dam risk criteria.

关键词： dam risk criteria acceptable risk annual probability of failure dam safety

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Deformation,structure and potential hazard of a landslide based on InSAR in Banbar county,Xizang(Tibet)

引用

China Geology 2024年第2期7卷 203-221页

作者： Guan-hua Zhao Heng-xing Lan Hui-yong Yin Lang-ping Li Alexander Strom Wei-feng Sun Chao-yang Tian College of Earth Science and engineering Shandong University of Science and TechnologyQingdao 266590China State Key Laboratory of resources and Environmental Information System Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of SciencesBeijing 100101China School of Geological engineering and Geomatics Chang’an UniversityXi’an 710054China Key Laboratory of Ecological Geology and Disaster Prevention Ministry of Natural ResourcesXi’an 710054China University of Chinese Academy of Sciences Beijing 100049China JSC“Hydroproject institute” Moscow 125993Russia

The Tibetan Plateau is characterized by complex geological conditions and a relatively fragile ecological *** recent years,there has been continuous development and increased human activity in the Tibetan Plateau region,leading to a rising risk of *** landslide in Banbar County,Xizang(Tibet),have been perturbed by ongoing disturbances from human engineering activities,making it susceptible to instability and displaying distinct *** this study,small baseline subset synthetic aperture radar interferometry(SBAS-InSAR)technology is used to obtain the Line of Sight(LOS)deformation velocity field in the study area,and then the slope-orientation deformation field of the landslide is obtained according to the spatial geometric relationship between the satellite’s LOS direction and the ***,the landslide thickness is inverted by applying the mass conservation *** results show that the movement area of the landslide is about 6.57×10^(4)m^(2),and the landslide volume is about 1.45×10^(6)m^(3).The maximum estimated thickness and average thickness of the landslide are 39 m and 22 m,*** thickness estimation results align with the findings from on-site investigation,indicating the applicability of this method to large-scale earth *** deformation rate of the landslide exhibits a notable correlation with temperature variations,with rainfall playing a supportive role in the deformation process and displaying a certain *** activities exert the most substantial influence on the spatial heterogeneity of landslide deformation,leading to the direct impact of several prominent deformation areas due to human ***,utilizing the long short-term memory(LSTM)model to predict landslide displacement,and the forecast results demonstrate the effectiveness of the LSTM model in predicting landslides that are in a continuous development and movement *** landslide is still active,and based

关键词： Landslide InSAR Human activity Deformation Structure LSTM model engineering construction Thickness Neural network Machine learning Prediction and prevention Tibetan Plateau Geological hazards survey engineering

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：