检索结果-南通市图书馆

维普期刊数据库

Understanding the iodine electrochemical behaviors in aqueous zinc batteries

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第2期101卷 402-415页

作者： Xuefang Xie Xiaoxin Xu Shuquan Liang Guozhao Fang College of Physical science and technology Xinjiang University xinjiang Key Laboratory of Solid State Physics and Devices Xinjiang University School of Materials science & Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province Central South University National Energy Metal Resources and New Materials Key Laboratory Central South University

Iodine is widely used in aqueous zinc batteries（ZBs） due to its abundant resources,low cost,and active redox *** addition to the active material in zinc-iodine batteries,iodine also plays an important role in other ZBs,such as regulating the electrochemical behavior of zinc ions,promoting the reaction kinetic and reversibility of other redox pairs,catalytic behaviors related to iodine reactions,coupling with other halogen ions,shuttle behaviors of polyiodides,***,there is currently a lack of comprehensive discussion on these ***,this review provides a comprehensive overview of the electrochemical behaviors of iodide in the aqueous *** effect of iodine ions on the Zn2+desolvation behaviors and the interfacial behaviors of Zn anode was *** redox pairs boosting other redox pairs,such as MnO2/Mn2+redox pair and vanadium redox pair to obtain high reversibility and capacity was also ***,the catalytic behaviors related to iodine reactions in aqueous ZBs,synergistic reaction with other halogen ions and suppression of shuttle behaviors for high performance zinc-iodine batteries were systematically ***,future prospects for designing effective iodine electrochemical behaviors with practicability are proposed,which will provide scientific guidance for the practical application of iodine-related aqueous ZBs.

关键词： Catalytic behavior Iodide ion Redox pairs Shuttle effect Zinc batteries

Na_(2)B_(6)SO_(13) with unprecedented [B_(6)SO_(13)]_(∞) double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B_(3)O_(7)] units

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

science China Chemistry 2025年第2期68卷 475-480页

作者： Jinbin Fan Ziting Yan Zilong Chen Huimin Li Zhihua Yang Fangfang Zhang Shilie Pan Research Center for Crystal Materials State Key Laboratory of Functional Materials and Devices for Special Environmental ConditionsXinjiang Key Laboratory of Functional Crystal MaterialsXinjiang Technical Institute of Physics and ChemistryChinese Academy of SciencesUrumqi 830011China Center of Materials science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Birefringence is crucial for birefringent crystals to modulate polarized light and nonlinear optical crystals to enable *** is closely related to the arrangement of advantageous functional groups with large microcosmic polarizability anisotropy in the ***,designing crystals with large birefringence by modulating the arrangement of advantageous functional groups is still a *** this work,the arrangement of the advantageous[B_(3)O_(7)]groups is optimized by introducing rigid tetrahedral[SO_(4)]groups,resulting in a novel boron-rich borosulfate,Na_(2)B_(6)SO_(13) ,which exhibits unprecedented[B_(6)SO_(13)]_(∞)double chain and an enhanced birefringence(Δn=0.07 at 589.3 nm)against the borate parent *** calculations confirm that the birefringence is mainly attributable to the uniform alignment of[B_(3)O_(7)]***_(2)B_(6)SO_(13) also possesses a deep ultraviolet(DUV)cutoff edge(λ<185 nm).This work provides a feasible method to design DUV birefringent crystals with large birefringence by inducing the arrangement of advantageous functional groups.

关键词： borosulfate deep ultraviolet birefringence modulated groups

Optimizing local search-based partial MaxSAT solving via initial assignment prediction

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

science China(Information sciences) 2025年第2期68卷 59-73页

作者： Chanjuan LIU Guangyuan LIU Chuan LUO Shaowei CAI Zhendong LEI Wenjie ZHANG Yi CHU Guojing ZHANG School of Computer science and technology Dalian University of Technology School of Software Beihang University Institute of Software Chinese Academy of Sciences School of Computer science Peking University

Partial maximum satisfiability(PMS) is a significant generalization of Boolean satisfiability(SAT) and maximum satisfiability(MaxSAT), by introducing hard clauses and soft clauses. Compared with SAT and MaxSAT, the PMS problem has more real-world applications where both hard and soft constraints are involved. Local search is an effective incomplete method for solving PMS and is useful for important domains where good-quality solutions are desired within reasonable *** local search PMS solvers, the approach for initial assignment generation is crucial because its effectiveness significantly affects practical performance. In this study, we propose a novel initial assignment prediction approach, called InitPMS. When predicting an assignment for PMS, InitPMS considers the specific structure of PMS instances, i.e., distinguishing hard and soft clauses. Our experiments on extensive PMS instances from MaxSAT evaluations(MSEs) 2020 and 2021 show that InitPMS significantly boosts the performance of five state-of-the-art local search PMS solvers, demonstrating its generality. In addition,our results indicate that incorporating InitPMS could improve the performance of one of the best incomplete PMS solvers in MaxSAT Evaluation 2021, indicating that InitPMS might help advance the state of the art in PMS solving.

关键词： MaxSAT local search initial assignment incomplete method assignment prediction

Study and application of the influence of inclination angle on the cross-fusion mechanism of high gas thick coal seam

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

International Journal of Mining science and technology 2025年第1期35卷 69-85页

作者： Pengxiang Zhao Zechen Chang Shugang Li Risheng Zhuo Yongyong Jia Qiudong Shao Wen Lei College of Safety science and Engineering Xi'an University of Science and TechnologyXi’an 710054China Western Mining Gas Intelligent Extraction Engineering Research Centre Xi’an 710054China xinjiang Coal and Coalbed Methane Engineering technology Research Centre Urumqi 830091China xinjiang Key Laboratory of Coal Mine Disaster Intelligent Prevention and Emergency Response Xinjiang Institute of EngineeringUrumqi 830023China xinjiang Uygur Autonomous Region Coal science Research Institute Urumqi 830091China xinjiang Changji Heze Tengda Mining Co. Ltd.Changji 831100China

In this study,to better decide the effect of coal seam dip angle upon the dynamic change of the crossfusion in gas transport and storage areas during the progress of working face in the high gas thick coal seam,a two-dimensional physical simulation experiment regarded as the theoretical research was conducted to properly explore the variation law of overburden *** results demonstrated that the boundary of the gas transport zone was located in the region of fracture *** boundary of the gas storage area was located in the abrupt penetration ***,according to the information theory,the state of the gas transport and storage areas was determined by the changing trend of the fracture rate and fracture *** mathematical representation model of the dip effect in gas transport and storage areas was *** criteria upon which the regional location of the gas transport area and gas storage area can be based were put *** cross-fusion evolution process of the dip effect in gas transport and storage areas was revealed as *** research results could provide guidance for realising directional and accurate gas extraction.

关键词： Coal seam dip angle Cross fusion High gas thick coal seam Overburden fracture Gas transport and storage areas

维普期刊数据库

A highly sensitive electrochemical sensor based on poly(3-aminobenzoic acid)/graphene oxide-gold nanoparticles modified screen printed carbon electrode for paraquat detection

在线全文

学校读者我要写书评

暂无评论

Journal of Environmental sciences 2025年第2期148卷 139-150页

作者： Dechnarong Pimalai Thitirat Putnin Suwussa Bamrungsap National Nanotechnology Center(NANOTEC) National Science and Technology Development Agency(NSTDA)Pathum Thani 12120Thailand

Herein,a modified screen printed carbon electrode(SPCE)based on a composite material,graphene oxide-gold nanoparticles(GO-AuNPs),and poly(3-aminobenzoic acid)(P3ABA)for the detection of paraquat(PQ)is *** modified electrode was fabricated by drop casting of the GO-AuNPs,followed by electropolymerization of 3-aminobenzoic acid to achieve SPCE/GO-AuNPs/*** morphology and microstructural characteristics of the modified electrodes were revealed by scanning electron microscopy(SEM)for each step of *** composite GO-AuNPs can provide high surface area and enhance electroconductivity of the *** addition,the presence of negatively charged P3ABA notably improved PQ adsorption and electron transfer rate,which stimulate redox reaction on the modified electrode,thus improving the sensitivity of PQ *** SPCE/GOAuNPs/P3ABA offered a wide linear range of PQ determination(10^(−9)-10^(−4) mol/L)and low limit of detection(LOD)of 0.45×10^(−9) mol/L or 0.116μg/L,which is far below international safety *** modified electrode showed minimum interference effect with percent recovery ranging from 96.5%to 116.1%after addition of other herbicides,pesticides,metal ions,and *** stability of the SPCE/GO-AuNPs/P3ABA was evaluated,and the results indicated negligible changes in the detection signal over 9 ***,this modified electrode was successfully implemented for PQ analysis in both natural and tapped water with high accuracy.

关键词： Paraquat Electrochemical sensor Graphene oxide(GO) Gold nanoparticle(AuNP) Poly(3-aminobenzoic acid)(P3ABA)

Catalytic production of high-energy-density spiro polycyclic jet fuel with biomass derivatives

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第2期101卷 760-768页

作者： Wen-Jing Zhang Yan-Cheng Hu Yan-Hong Tan Jia Li Ning Li Jing-Pei Cao School of Chemical Engineering and technology China University of Mining and Technology CAS Key Laboratory of science and technology on Applied Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences

High-energy-density（HED） fuel（*** used JP-10 and RJ-4）,featuring compact 3D polycyclic structure with high strain,is of critical importance for volume-limited military aircraft,since their high density and combustion heat can provide more propulsion *** reduce the reliance on petroleum source,it is highly desirable to develop renewable alternatives for the production of strained polycyclic HED fuel,but which remains a big challenge because of the inaccessibility caused by the high strain,We herein demonstrate a three-step catalytic route towards highly strained C17and C18spirofuel with biomass *** process includes catalytic aldol condensation of renewable cyclohexanone/cyclopentanone with benzaldehyde,catalytic spiro Diels-Alder（D-A） reaction of aldol adduct with isoprene,and catalytic *** key spiro D-A reaction is enabled by the catalysis of heterogeneous Lewis acidic ionic *** chloroaluminate IL,formed by benign urea and AICl3,exhibits good catalytic performance and reusability for this *** eventual hydrodeoxygenation（HDO）over Pd/C and H-Y produces strained tricyclic spirofuel with density>0.93 g/mL,combustion heat>41 MJ/L and freezing point <-40℃,which are better than the properties of tactical fuel ***,it is anticipated that the as-prepared renewable fuels have the potential to replace traditional petroleum-derived HED fuels.

关键词： Biomass derivatives Cycloaddition High-energy-density Lewis acidic ionic liquid Spiro polycyclic fuel

The mechanisms of pH regulation on promoting volatile fatty acids production from kitchen waste

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Environmental sciences 2025年第1期147卷 414-423页

作者： Feng Liu Tingting Wang Leiyu Feng Yinguang Chen College of Environmental science and Engineering Tongji UniversityShanghai 200092China TUS-Environmental science and technology development Co. Ltd.Beijing 100084China

The anaerobic acid production experiments were conducted with the pretreated kitchen waste under pH *** results showed that pH 8 was considered to be the most suitable condition for acid production,especially for the formation of acetic acid and propionic *** average value of total volatile fatty acid at pH 8 was 8814 mg COD/L,1.5 times of that under blank *** average yield of acetic acid and propionic acid was 3302 mg COD/L and 2891 mg COD/L,*** activities of key functional enzymes such as phosphotransacetylase,acetokinase,oxaloacetate transcarboxylase and succinylcoA transferase were all *** further explore the regulatory mechanisms within the system,the distribution of microorganisms at different levels in the fermentation system was obtained by microbial sequencing,results indicating that the relative abundances of Clostridiales,Bacteroidales,Chloroflexi,Clostridium,Bacteroidetes and Propionibacteriales,which were great contributors for the hydrolysis and acidification,increased rapidly at pH 8 compared with the blank ***,the proportion of genes encoding key enzymes was generally increased,which further verified the mechanism of hydrolytic acidification and acetic acid production of organic matter under pH regulation.

关键词： Kitchen waste Acid fermentation Volatile fatty acids pH regulation Functional genes

Spatial-temporal distribution and emission of urban scale air pollutants in Hefei based on Mobile-DOAS

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Environmental sciences 2025年第5期151卷 238-251页

作者： Zhidong Zhang Pinhua Xie Ang Li Min Qin Jin Xu Zhaokun Hu Xin Tian Feng Hu Yinsheng Lv Jiangyi Zheng Youtao Li School of Environmental science and Optoelectronic technology University of Science and Technology of ChinaHefei 230026China Key Laboratory of Environmental Optics and technology Anhui Institute of Optics and Fine MechanicsHefei Institutes of Physical ScienceChinese Academy of SciencesHefei 230031China University of Chinese academy of sciences Beijing 100049China Information Materials and Intelligent Sensing Laboratory of Anhui Province Institutes of Physical Science and Information TechnologyAnhui UniversityHefei 230601China

As a significant city in the Yangtze River Delta regions,Hefei has experienced rapid changes in the sources of air pollution due to its high-speed economic development and urban ***,there has been limited research in recent years on the spatial-temporal distribution and emission of its atmospheric *** address this,this study conducted mobile observations of urban roads using the Mobile-DOAS instrument from June 2021 to May *** monitoring results exhibit a favourable consistent with TROPOMI satellite data and ground monitoring station ***,there were pronounced seasonal variations in air ***,high concentration of HCHO and NO_(2)were closely associated with traffic congestion on roadways,while heightened SO_(2)levels were attributed to winter heating and industrial *** study also revealed that with the implementation of road policies,the average vehicle speed increased by 95.4%,while the NO concentration decreased by 54.4%.In the estimation of urban NO_(x)emission flux,it was observed that in temporal terms,compared with inventory data,the emissions calculated viamobile measurements exhibitedmore distinct seasonal patterns,with the highest emission rate of 349 g/sec in winter and the lowest of 142 g/sec in *** spatial terms,the significant difference in emissions between the inner and outer ring roads also suggests the presence of the city’s primary NO_(x)emission sources in the area between these two *** study offers data support for formulating the next phase of air pollution control measures in urban areas.

关键词： Mobile-DOAS HCHO NO_(2) SO_(2) Spatial-temporal distribution NOx emission

Perspectives on additive manufacturing for warhead applications

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Defence technology(防务技术) 2025年第1期43卷 225-251页

作者： Hao Xue Qiang Zhou Chuan Xiao Guangyan Huang State Key Laboratory of Explosion science and technology Beijing Institute of TechnologyBeijing 100081China Ordnance science and Research academy of China Beijing 100089China Beijing Institute of technology Chongqing Innovation Center Chongqing 401120China

According to different damage modes,warheads are roughly divided into three types:fragmentation warheads,shaped charge warheads,and penetrating *** to limitations in material and structural manufacturing,traditional manufacturing methods make it difficult to fully utilize the damage ability of the *** manufacturing(AM)technology can fabricate complex structures,with classified materials composition and customized components,while achieving low cost,high accuracy,and rapid production of the *** maturity of AM technology has brought about a new round of revolution in the field of *** this paper,we first review the principles,classifications,and characteristics of different AM *** development trends of AM technologies are pointed out,including multi-material AM technology,hybrid AM technology,and smart AM *** our survey,PBF,DED,and EBM technologies are mainly used to manufacture warhead damage *** and DIW technologies are mainly used to manufacture warhead ***,the research on the application of AM technology in three types of warhead and warhead charges was reviewed and the existing problems and progress of AM technologies in each warhead were ***,we summarized the typical applications and look forward to the application prospects of AM technology in the field of warheads.

关键词： Additive manufacturing Fragmentation warhead Shaped charge warhead Penetrating warhead Warhead charge

维普期刊数据库